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Structure of Triammonium fac-Trichloridotrioxidorhenate(VII) Chloride with C 3v Crystallographic Symmetry of the Complex Anion

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Abstract

The unstable crystals of triammonium fac-trichloridotrioxidorhenate(VII) chloride have been obtained from ammonium rhenate(VII) solution in concentrated hydrochloric acid. The crystal structure consists of fac-trichloridotrioxidorhenate(VII) anions, chloride anions and ammonium cations. Each fac-trichloridotrioxidorhenate(VII) anion and each chloride anion lies in special position of 3m site symmetry (cell parameters: a = 9.026(3) Å; c = 7.690(4) Å; space group: P63 mc). The ammonium cation lies in special position of m site symmetry. The following anion geometrical parameters of the fac-trichloridotrioxidorhenate(VII) anion have been obtained: Re–O bond length of 1.720(2) Å, Re–Cl bond length of 2.5428(9) Å, the bond angles: O–Re–O of 103.5(1)° and Cl–Re–Cl of 79.8(1)°.

Graphical Abstract

In the title crystal the fac-trichloridotrioxidorhenate(VII) anion adopts its highest possible C 3v symmetry.

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Acknowledgements

Financial support from Ministry of Science and Higher Education (project number N204 130 32/3318).

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  1. Faculty of Chemistry, University of Wrocław, 14 Joliot-Curie St, 50-383, Wrocław, Poland

    Małgorzata Hołyńska & Tadeusz Lis

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  1. Małgorzata Hołyńska
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  2. Tadeusz Lis
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Correspondence to Małgorzata Hołyńska.

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Hołyńska, M., Lis, T. Structure of Triammonium fac-Trichloridotrioxidorhenate(VII) Chloride with C 3v Crystallographic Symmetry of the Complex Anion. J Chem Crystallogr 40, 707–711 (2010). https://doi.org/10.1007/s10870-010-9776-9

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