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N–H···π Interactions in Two Isomers of an Amino Group Containing bis-Phenol

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Abstract

Crystal structures of two bis-phenols namely bis-(3,5-dimethyl-2-hydroxyphenyl)(3-amino phenyl)methane 1 and bis-(3,5-dimethyl-4-hydroxyphenyl)(3-aminophenyl) methane 2 are determined. The compound 1 crystallises in monoclinic P21/c with a = 12.2579(16) Å, b = 16.0906(19) Å, c = 10.6664(13) Å, β = 115.417(7)°, V = 1900.2(4) Å3 whereas 2 crystallizes in monoclinic C2/c, a = 9.2538(2) Å, b = 18.6579(4) Å, c = 23.2725(5) Å, β = 98.796(2)°, V = 3970.89(15) Å3. The crystal lattice of both the compounds shows presence of N–H···π interactions but no O–H···π interactions.

Graphical Abstract

N–H···π interactions in bis-(3,5-dimethyl-2-hydroxyphenyl)(3-amino phenyl)methane.

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Fig. 1
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Acknowledgments

Authors thanks Council of Scientific and Industrial Research, New-Delhi, India for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781 039, Assam, India

    Gautam Prasanna Kar, Anirban Karmakar & Jubaraj B. Baruah

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  1. Gautam Prasanna Kar
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  2. Anirban Karmakar
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  3. Jubaraj B. Baruah
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Correspondence to Jubaraj B. Baruah.

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Kar, G.P., Karmakar, A. & Baruah, J.B. N–H···π Interactions in Two Isomers of an Amino Group Containing bis-Phenol. J Chem Crystallogr 40, 702–706 (2010). https://doi.org/10.1007/s10870-010-9775-x

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  • DOI: https://doi.org/10.1007/s10870-010-9775-x

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