Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structures of Two Binuclear Lanthanide [Ln = Pr, Dy] Complexes with 4-Quinolineacarboxylate

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The reaction of the organic ligand, 4-quinolineacarboxylate (L) with Pr(ClO4)3·6H2O and Dy(ClO4)3·6H2O, leads to the formation of two novel complexes [Pr2(L)6(H2O)4]2H2O 1 and [Dy2(L)6(H2O)4]2H2O 2, which have been characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis (monoclinic system, space group P2(1)/n, with a = 11.805(2), b = 16.645(3), c = 15.367(3) Å, β = 106.78(3)°, V = 2891.1(10) Å3, Z = 4 for 1, monoclinic system, space group P2(1)/n, with a = 11.629(2), b = 16.478(3), c = 5.336(3) Å, β = 105.83°, V = 2827.4(10) Å3, Z = 4). The two isostructure complexes are binuclear and possess an inversion center which is at the midpoint of the linkage of two symmetrical La(III) centers. In two complexes, each metal center adopts nine-coordinated mode coordinated by nine O atoms from two H2O molecules and three carboxyls of three ligands, and L displays three different coordination modes. Hydrogen bonds join the binuclear complexes into 3D networks.

Graphical Abstract

The structures of two binuclear lanthanide [Ln = Pr, Dy] complexes with 4-quinolineacarboxylate were solved by X-ray diffraction analysis, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Scheme 1
Fig. 3

Similar content being viewed by others

References

  1. Zhai B, Yi L, Wang HS, Zhao B, Cheng P, Liao DZ, Yan SP (2006) Inorg Chem 45:8471

    Article  CAS  Google Scholar 

  2. Sun HL, Ye CH, Wang XY, Li JR, Gao S, Yu KB (2004) J Mol Struct 702:77

    Article  CAS  Google Scholar 

  3. Lia DJ, Wang SP, Liao DZ, Jiang ZH, Yan SP (2004) J Mol Struct 698:103

    Article  Google Scholar 

  4. Shi W, Chen XY, Zhao B, Yu A, Song HB, Cheng P, Wang HG, Liao DZ, Yan SP (2006) Inorg Chem 45:3949

    Article  CAS  Google Scholar 

  5. Chandler BD, Cramb DT, Shimizu GKH (2006) J Am Chem Soc 128:10403

    Article  CAS  Google Scholar 

  6. de Sá GF, Malta OL, de Mello Donegá C, Simas AM, Longo RL, Santa-Cruz PA, da Silva EF (2000) Coord Chem Rev 196:165

    Article  Google Scholar 

  7. Lai WPW, Wong WT, Lic BKF, Cheah KW (2002) New J Chem 26:576

    Article  CAS  Google Scholar 

  8. Lin X, Blake AJ, Wilson C, Sun XZ, Champness NR, George MW, Hubberstey P, Mokaya R, Schröder M (2006) J Am Chem Soc 128:10745

    Article  CAS  Google Scholar 

  9. Zhao JP, Hu BW, Liu FC, Hu X, Zeng YF, Bu XH (2007) CrystEngComm 9:902

    Article  CAS  Google Scholar 

  10. Wang J, Huang MH, Cheng WD, Liu P (2007) Chin J Struct Chem 26:33

    Google Scholar 

  11. Bu XH, Tong ML, Xie YB, Li JR, Chang HC, Kitagawa S, Ribas J (2005) Inorg Chem 26:9837

    Article  Google Scholar 

  12. Chen ZF, Zhang P, Xiong RG, Liu DJ, You XZ (2002) Inorg Chem Commun 5:35

    Article  Google Scholar 

  13. Abu-Youssef MAM, Langer V (2006) Polyhedron 25:1187

    Article  CAS  Google Scholar 

  14. Costes JP, Clemente-Juan JM, Dahan F, Nicodème F, Verelst M (2002) Angew Chem Int Ed 41:323

    Article  CAS  Google Scholar 

  15. Sheldrick GM (1997) SHELXS-97, program for X-ray crystal structure solution, University of Göttingen, Germany

  16. Sheldrick GM (1997) SHELXL-97, Program for X-ray crystal structure refinement, University of Göttingen, Germany

  17. Deacon GB, Phillips R (1980) Coord Chem Rev 33:227

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This work was supported by the Beijing Municipal Natural Science Foundation (No. 2082004) and the Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality (PHR 200907105).

Author information

Authors and Affiliations

  1. College of Environmental and Energy Engineering, Beijing University of Technology, Beijing, 100022, China

    Qian Gao, Ya-Bo Xie & Chao-Yan Zhang

Authors
  1. Qian Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ya-Bo Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chao-Yan Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ya-Bo Xie.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gao, Q., Xie, YB. & Zhang, CY. Synthesis and Crystal Structures of Two Binuclear Lanthanide [Ln = Pr, Dy] Complexes with 4-Quinolineacarboxylate. J Chem Crystallogr 40, 872–876 (2010). https://doi.org/10.1007/s10870-010-9757-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-010-9757-z

Keywords

Search

Navigation