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Synthesis and Crystal Structure of Bis {2-[(cyclohexylimino)methyl]-4,6-dihydroselenophenol}copper(II)

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Abstract

A new Schiff base complex, Bis {2-[(cyclohexylimino)methyl]-4,6-dihydroselenophenol}copper(II), has been synthesized and structurally characterized by elemental analyses and X-ray diffraction. The title complex C26H32N2O2·Se4Cu crystallizes in the monoclinic space group P21/c with the cell parameters a = 15.308(3) Å, b = 12.857(2) Å, c = 14.161(3) Å, β = 93.23(3)°, V = 2782.8(10) Å3 and Z = 4. The central Copper(II) atom is four-coordinated by two O and two N atoms from the two Schiff base ligands, 2-[(cyclohexylimino)methyl]-4,6-dihydroselenophenol, forming a distorted square-planar coordination.

Graphical Abstract

A new Schiff base complex, Bis {2-[(cyclohexylimino)methyl]-4,6-dihydroselenophenol}copper(II), has been synthesized and structurally characterized by elemental analyses and X-ray diffraction. The central Copper(II) atom is four-coordinated by two O and two N atoms from the two Schiff base ligands, 2-[(cyclohexylimino)methyl]-4,6-dihydroselenophenol, forming a distorted square-planar coordination.

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Acknowledgments

The work was financed by a grant (Project 30772627) from National Natural Science Foundation of China.

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Authors and Affiliations

  1. Key Laboratory of Anhui Educational Department, Anhui University of Technology, 243002, Maanshan, People’s Republic of China

    Lei Shi & Hai-Liang Zhu

  2. State Key Laboratory of Pharmaceutical Biotechnology, Nanjing University, 210093, Nanjing, People’s Republic of China

    Lei Shi & Hai-Liang Zhu

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  1. Lei Shi
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  2. Hai-Liang Zhu
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Correspondence to Hai-Liang Zhu.

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Shi, L., Zhu, HL. Synthesis and Crystal Structure of Bis {2-[(cyclohexylimino)methyl]-4,6-dihydroselenophenol}copper(II). J Chem Crystallogr 40, 384–386 (2010). https://doi.org/10.1007/s10870-010-9715-9

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  • DOI: https://doi.org/10.1007/s10870-010-9715-9

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