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Poly (Isonicotinic Acid N-Oxide–Isonicotinate-N-Oxide-Chloro-Uranyl): The Interpenetrating Grids Created by Coordination and Hydrogen Bonds

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Abstract

The building blocks of the title compound, [UO2 2+·Cl−·(C6H4NO3)− · (C6H5NO3)]n–uranyl fragment, chloride ion, one deprotonated isonicotinate N-oxide and one isonicotinic acid N-oxide, are arranged in the complicated three dimensional network by means of both coordination and hydrogen bonds. The uranium ion is seven-coordinated, in the fashion intermediate between the pentagonal bipyramid and capped octahedron. The coordination one-dimensional polymer chains are connected by strong carboxyl—carboxyl hydrogen bonds into two dimensional grids. These grids interpenetrate each other like the chain-links.

Graphical Abstract

The coordination one-dimensional polymer chains are connected by strong carboxyl—carboxyl hydrogen bonds into two dimensional grids, which interpenetrate each other like the chain-links.

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Authors and Affiliations

  1. Department of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland

    Stefan Lis, Zbigniew Glatty & Maciej Kubicki

  2. RER Consultants, Schiessstattweg 3a, D-94032, Passau, Germany

    Guenther Meinrath

Authors
  1. Stefan Lis
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  2. Zbigniew Glatty
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  3. Guenther Meinrath
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  4. Maciej Kubicki
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Correspondence to Maciej Kubicki.

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Lis, S., Glatty, Z., Meinrath, G. et al. Poly (Isonicotinic Acid N-Oxide–Isonicotinate-N-Oxide-Chloro-Uranyl): The Interpenetrating Grids Created by Coordination and Hydrogen Bonds. J Chem Crystallogr 40, 646–649 (2010). https://doi.org/10.1007/s10870-010-9711-0

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  • DOI: https://doi.org/10.1007/s10870-010-9711-0

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