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Synthesis, Characterization and Crystal Structure of 4,5-Bis(Cyclohexanecarbonylthio)-1,3-dithiolane-2-thione Crystal

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Abstract

A new crystal of 4,5-bis(cyclohexanecarbonylthio)-1,3-dithiolane-2-thione has been prepared at room temperature and characterized by elemental analysis, UV–Vis–NIR absorption spectrum and X-ray single crystal determination. The complex crystallized in triclinic space group P-1 with unit cell dimensions a = 5.37370(10) Å, b = 12.8618(2) Å, c = 15.2481(2) Å, α = 74.8530(10)°, β = 80.6000(10)°, γ = 85.9550(10)°, V = 1003.18(3) Å3, Z = 2, D x = 1.3861(1) g cm−3. The X-ray structure determination revealed that the crystal is centered-symmetrical and the molecules form dimers with a long intermolecular S···S interaction in the crystal.

Graphical Abstract

A new crystal of 4,5-bis(cyclohexanecarbonylthio)-1,3-dithiolane-2-thione with triclinic space group P − 1 [unit cell dimensions a = 5.37370(10) Å, b = 12.8618(2) Å, c = 15.2481(2) Å, α = 74.8530(10)º,β = 80.6000(10)º, γ = 85.9550(10)º, V = 1003.18(3) Å3, Z = 2, D x = 1.3861(1) g·cm−3] has been prepared and characterized by elemental analysis, UV–Vis–NIR absorption spectrum and X-ray single crystal determination.

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Acknowledgments

The authors acknowledge the financial support of the High Technology Development Project of China (grant No. 2007AA090701-4), National Key Science and Technology Project of China (grant Nos. 2008ZX05024-02-005, 2008ZX05002-005), the Postdoctoral Science Foundation of China (grant No. 20090451347), National Outstanding Youth Foundation of China (grant No. 50925414) and Outstanding Research Award Fund for Young Scientist of Shandong Province (grant No. BS2009CL019).

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Authors and Affiliations

  1. School of Petroleum Engineering, China University of Petroleum (East China), 266555, Qingdao, People’s Republic of China

    Yan Ling Wang, Jun Yao, Ye Fei Wang, Jing Jing Zheng & Li Ma

  2. Material Science and Engineering of Shandong Institute of Light Industry, 250353, Jinan, People’s Republic of China

    Mei Li

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  1. Yan Ling Wang
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  2. Mei Li
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Correspondence to Yan Ling Wang.

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Wang, Y.L., Li, M., Yao, J. et al. Synthesis, Characterization and Crystal Structure of 4,5-Bis(Cyclohexanecarbonylthio)-1,3-dithiolane-2-thione Crystal. J Chem Crystallogr 40, 501–504 (2010). https://doi.org/10.1007/s10870-010-9685-y

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  • DOI: https://doi.org/10.1007/s10870-010-9685-y

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