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Investigation of Isomeric Polymers [Cd2(mbt)4] n and [Cd(mbt)2] n : The Crystal Structure of Catena-tetra (2-Mercaptobenzothiazole) Dicadmium, {[Cd(μ-η2-C7H4NS2)2][Cd(μ-η2-C7H4NS2) (μ3-η2-C7H4NS2)]} n

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Abstract

Isomeric polymers [Cd2(mbt)4] n and [Cd(mbt)2] n (mbt = mercaptobenzothiazole) are investigated. The complex {[Cd(μ-η2-C7H4NS2)2][Cd(μ-η2-C7H4NS2) (μ-η3-C7H4NS2)]} n is formed by the reaction of Cd(NO3)2·4H2O with 2-Hmbt in the presence of H2biim in EtOH/H2O. The complex crystallizes in the orthorhombic space group Pca2(1), where a = 21.892(2), b = 9.8994(11), c = 14.8687(15) Å, α = 90, β = 90, γ = 90º, V = 3,222.3(6) Å3, and Z = 4. The two Cd atoms, one exhibits a CdN2S2 tetrahedral geometry and the other exhibits a distorted CdN2S3 trigonal bipyramidal geometry, are linked by bridging–chelating mbt and bridging mbt ligands.

Graphical Abstract

The infinite 1D polymer chains complex {[Cd(μ-η2-C7H4N2S2)2][Cd(μ-η2-C7H4NS2) (μ3-η2-C7H4NS2)]} n is formed by the reaction of Cd(NO3)2·4H2O, 2-Hmbt in the present of H2biim, which contains a CdN2S2 tetrahedral geometry and a distorted CdN2S3 trigonal bipyramidal geometry.

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Acknowledgments

This work has been supported by the National Science Foundation of China (grant no. 20871085), the Committee of Education of Beijing Foundation of China (grant no. KM200610028006), the Project-sponsored by SRF for ROCS and SEM, the subsidy of Beijing Personnel Bureau, National Keystone Basic Research Program (973 Program) under grant no. 2007CB310408, no. 2006CB302901 and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences.

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  1. Department of Chemistry, Capital Normal University, 100048, Beijing, People’s Republic of China

    Qiong-Hua Jin, Li-Li Zhou, Li-Jun Xu & Xiao-Ming Lu

  2. Department of Physics, Capital Normal University, 100048, Beijing, People’s Republic of China

    Cun-Lin Zhang

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  2. Li-Li Zhou
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Jin, QH., Zhou, LL., Xu, LJ. et al. Investigation of Isomeric Polymers [Cd2(mbt)4] n and [Cd(mbt)2] n : The Crystal Structure of Catena-tetra (2-Mercaptobenzothiazole) Dicadmium, {[Cd(μ-η2-C7H4NS2)2][Cd(μ-η2-C7H4NS2) (μ3-η2-C7H4NS2)]} n . J Chem Crystallogr 40, 432–436 (2010). https://doi.org/10.1007/s10870-009-9673-2

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