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Crystal Structure of 4-Bromo-3,4-Dichloro-1-(1-Morpholinyl)-1-(Decylsulfanyl)-2-Nitro-Buta-1,3-Diene

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The compound 4-bromo-3,4-dichloro-1-(1-morpholinyl)-1-(decylsulfanyl)-2-nitro-buta-1,3-diene was synthesized from the reaction of 4-bromo-1,3,4-trichloro-1-(decylsulfanyl)-2-nitro-buta-1,3-diene with morpholine and characterized by elemental analysis, IR spectrum, UV spectra, 1H NMR,13C NMR and X-ray single crystal determination. In the title compound, C18H29BrCl2N2O3S, crystallizes in the monoclinic space group P21/c, a = 15.8326(4) Å, b = 8.9915(10) Å, c = 16.7528(5) Å, β = 100.808(10)°, V = 2,342.6(3) Å3, Z = 4, R 1 = 0.0590 and wR 2 = 0.0940. The morpholine ring adopts a chair conformation. The morpholine ring and the butadiene group are inclined at an angle of 113.4 (1)°. The butadiene unit is not planar as can be expected if the two double bonds are fully conjugated.

Graphical Abstract

The title compound, C18H29BrCl2N2O3S, crystallizes in the monoclinic space group P21/c. The structure of the compound contains the expected nitro group is substituted to butadienyl skeleton, the alkylsulfanyl chain and the morpholine ring.

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  1. Further information may be obtained from: Cambridge Crystallographic Data Center (CCDC), 12 Union Road, Cambridge CB21EZ, UK, by quoting the depository number CCDC-723246. E-mail:


  1. Nadler G, Faivre JF, Forest MC, Cheval B, Martin M, Souchet M, Gout B, Bril A (1998) Bioorg Med Chem 6:1993

    Article  CAS  Google Scholar 

  2. Taguchi M, Kondo H, Inoue Y, Kawahata Y, Jinbo Y, Sakamoto F, Tsukamoto G (1992) J Med Chem 35:94

    Article  CAS  Google Scholar 

  3. Ibis C, Deniz NG (2007) Indian J Chem 46(4):674

    Google Scholar 

  4. Ibis C, Tuyun AF, Aydinli G (2009, in press) Phosphorus Sulfur Silicon Relat Elem

  5. Altomare A, Cascarano G, Giacovazzo C, Guagliardi A, Burla M, Polidori G, Camalli M (1994) J Appl Crystallogr 27:435

    Google Scholar 

  6. Betteridge PW, Carruthers JR, Cooper RI, Prout K, Watkin DJJ (2003) J Appl Crystallogr 36:1487

    Article  CAS  Google Scholar 

  7. Farrugia LJ (1997) J Appl Crystallogr 30:565

    Article  CAS  Google Scholar 

  8. Ibis C, Deniz NG (2006) Acta Crystallogr E62:o5373

    CAS  Google Scholar 

  9. Ibis C, Deniz NG (2007) Acta Crystallogr E63:o3058

    CAS  Google Scholar 

  10. Ibis C, Sayil MC, Ozkok F (2006) Acta Crystallogr E62:o1147

    CAS  Google Scholar 

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The author greatly acknowledges Research Fund of Istanbul University for financial support.

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Correspondence to Cemil Ibis.

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Ibis, C., Deniz, N.G. & Tuyun, A.F. Crystal Structure of 4-Bromo-3,4-Dichloro-1-(1-Morpholinyl)-1-(Decylsulfanyl)-2-Nitro-Buta-1,3-Diene. J Chem Crystallogr 40, 353–356 (2010).

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