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Crystal Structures and Properties of Bis(2-Aminopyrimidine-N-)-Bis(Thiocyanato-N)Zinc(II) and Catena-[2-Aminopyrimidine-N- (μ-Thiocynanto-S,N)(Thiocyanato-S)Cadmium(II)]

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Abstract

Complexes [Zn(NCS)2(2-AMP)2] (2-AMP = 2-aminopyrimidine) 1 and [Cd(SCN)2(2-AMP)2]n 2 are prepared and characterized by X-ray crystallographic methods. 1 crystallizes in the monoclinic, space group C2/c, with a = 13.5761(14), b = 8.3330(10), c = 13.5962(15) Å, β = 99.5450(10)°, V = 1516.8(3) Å3, Z = 4. In 1, the zinc atom is coordinated by four N atoms from two AMP and two NCS−. 2 crystallizes in the monoclinic, space group C2/c, with a = 9.7259(11), b = 19.332(2), c = 8.2149(9) Å, β = 99.817(2)°, V = 1522.0(3) Å3, Z = 4. Complex 2 is made up of 1D chains along a-axis. Each Cd is attached to four NCS− bridges and two pendant 2-AMP ligands.

Graphical Abstract

A mononuclear complex bis(2-aminopyrimidine-N-)-bis(thiocyanato-N)zinc(II) 1 and 1D chains complex catena-[2-aminopyrimidine-N- (μ-thiocynanto-S,N)(thiocyanato-S)cadmium(II)] 2 are prepared and characterized by X-ray crystallographic methods and NMR, IR, fluorescence, TG and DTA techniques.

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Acknowledgments

This work has been supported by the National Science Foundation of China (grant no. 20871085), the Committee of Education of Beijing Foundation of China (grant no. KM200610028006), the Project-sponsored by SRF for ROCS and SEM, the subsidy of Beijing Personnel Bureau, National Keystone Basic Research Program (973 Program) under grant no. 2007CB310408, no. 2006CB302901 and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences.

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Authors and Affiliations

  1. Department of Chemistry, Capital Normal University, Beijing, 100048, People’s Republic of China

    Qiong-Hua Jin, Jing-Jing Sun, Jie-Qiang Wu & Yong-Cheng Dai

  2. Department of Physics, Capital Normal University, Beijing, 100048, People’s Republic of China

    Cun-Lin Zhang

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  1. Qiong-Hua Jin
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  2. Jing-Jing Sun
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Correspondence to Qiong-Hua Jin.

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Jin, QH., Sun, JJ., Wu, JQ. et al. Crystal Structures and Properties of Bis(2-Aminopyrimidine-N-)-Bis(Thiocyanato-N)Zinc(II) and Catena-[2-Aminopyrimidine-N- (μ-Thiocynanto-S,N)(Thiocyanato-S)Cadmium(II)]. J Chem Crystallogr 40, 310–315 (2010). https://doi.org/10.1007/s10870-009-9652-7

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