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Chloro-Bridged Dimeric Cadmium(II)-Isothiocyanate Complex with a Tridentate NNN Type Ligand: Synthesis, X-ray Structure, Thermal Analysis

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Abstract

The dinuclear cadmium(II) complex with 2,6-bis(3,4,5-trimethyl-N-pyrazolyl)pyridine (btmpp) has been synthesized, and characterized by single crystal X-ray diffraction, IR, UV–Vis and TGA–DTA methods. Cd atoms are located in a distorted octahedral environment in the complex. The complex crystalizes in monoclinic space group C 2/c, with unit cell dimensions a = 20.5636(12) Å, b = 14.0167(13) Å, c = 15.6598(11) Å, β = 113.425(5)o, V = 4141.7(5) Å3. There are two intermolecular and a intramolecular hydrogen bonds interactions in crystal.

Index Abstract

A new chloro-bridged Cd(II)-isothiocyanato complex with NNN type ligand synthesized and characterized by FT-IR, UV–Vis, single crystal X-ray and thermal analysis.

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Acknowledgments

The financial support of the Scientific and Technical Research Council of Turkey (TUBITAK-TBAG (108T622), and Balikesir University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Balikesir University, Cagis, 10145, Balikesir, Turkey

    Çiğdem Hopa, Mahir Alkan & Raif Kurtaran

  2. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Samsun, Turkey

    Canan Kazak & N. Burcu Arslan

Authors
  1. Çiğdem Hopa
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  2. Mahir Alkan
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  3. Canan Kazak
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  4. N. Burcu Arslan
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Correspondence to Raif Kurtaran.

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Hopa, Ç., Alkan, M., Kazak, C. et al. Chloro-Bridged Dimeric Cadmium(II)-Isothiocyanate Complex with a Tridentate NNN Type Ligand: Synthesis, X-ray Structure, Thermal Analysis. J Chem Crystallogr 40, 160–164 (2010). https://doi.org/10.1007/s10870-009-9625-x

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  • DOI: https://doi.org/10.1007/s10870-009-9625-x

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