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Synthesis and Crystal Structure of 2,4-Diiodo-6-[(2-morpholin-4-yl-ethylimino)-methyl]-phenolato-zinc(II)

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Abstract

One new complex, 2,4-Diiodo-6-[(2-morpholin-4-yl-ethylimino)- methyl]- phenolato-zinc(II) has been designed and synthesized. The structure was determined by UV, IR and single X-ray crystallography study. The title complex C26H30O4N4I4Zn crystallizes in the triclinic space group P − 1 with the cell parameters a = 9.938(2) Å, b = 11.937(2) Å, c = 14.527(3) Å, α = 87.14(3)°, β = 79.03(3)°, γ = 76.20(3)°, V = 1565.1(5) Å3 and Z = 2. The central zinc(II) is four coordinate and bonds to two nitrogen atoms and two oxygen atoms from two 3,5-diiodosalicylaldehyde-2- morpholinoethylamine Schiff bases. The complex is linked into a column by weak intermolecular interactions.

Graphical Abstract

The title complex C26H30O4N4I4Zn crystallizes in the triclinic space group P−1 with the cell parameters a = 9.938(2) Å, b = 11.937(2) Å, c = 14.527(3) Å, α = 87.14(3)°, β = 79.03(3)°, γ = 76.20(3)°, V = 1565.1(5) Å3 and Z = 2. The central zinc(II) is four coordinate and bonds to two nitrogen atoms and two oxygen atoms from two 3,5-diiodosalicylaldehyde-2-morpholinoethylamine Schiff bases.

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Acknowledgments

The work was co-financed by grant (Project 30772627) from National Natural Science Foundation of China, and by grant (Project 070416274X) from Anhui Natural Science Foundation, Anhui Province, China.

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Authors and Affiliations

  1. Key Laboratory of Anhui Educational Department, Anhui University of Technology, Maanshan, 243002, People’s Republic of China

    Suo-Ping Xu & Hai-Liang Zhu

  2. School of Chemistry and Chemical Engineering, Xuzhou Normal University, Xuzhou, 221116, People’s Republic of China

    Suo-Ping Xu

  3. School of Life Sciences, Nanjing University, Nanjing, 210093, People’s Republic of China

    Peng-Cheng Lv, Rui-Qin Fang, Lei Shi & Hai-Liang Zhu

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  1. Suo-Ping Xu
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  2. Peng-Cheng Lv
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Correspondence to Hai-Liang Zhu.

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Xu, SP., Lv, PC., Fang, RQ. et al. Synthesis and Crystal Structure of 2,4-Diiodo-6-[(2-morpholin-4-yl-ethylimino)-methyl]-phenolato-zinc(II). J Chem Crystallogr 39, 931–934 (2009). https://doi.org/10.1007/s10870-009-9612-2

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