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Synthesis, Crystal Structure of catena-poly [[4,4′-bipyridine-N,N′-bis[(triphenylphosphine)-copper(I)]-pyridine-2-carbaldehyde azine-N,N′:N″,N′″] bis(tetrafluoroboride)]

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Abstract

The title complex [Cu2(C10H8N2)(C12H10N4)(C18H15)2(BF4)2] n has been synthesized and characterized by single crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/c with a = 10.450(4) Å, b = 14.027(5) Å, c = 18.950(6) Å, β = 100.459(5)°, V = 2,731.7(16) Å3. In the title complex, the cation forms a linear chain, which is bridged by 4,4′-bipyridine and pyridine-2-carbaldehyde azine. The crystallographic asymmetry unit could be expanded polymeric structure using symmetry code: x, 1 + y, z; 1 − x, −y, 1 − z. The Cu(I) atom is coordinated by one P atom of PPh3 ligand, two N atoms of pyridine-2-carbaldehyde azine ligand and one N atom of 4,4′-bipyridine ligand. There is a crystallographic centre of symmetry at the mid-point of the C–C bond between two pyridine rings of 4,4′-bipyridine.

Graphical Abstract

A linear chain complex [Cu2(C10H8N2)(C12H10N4)(C18H15)2(BF4)2] n has been synthesized and characterized by single crystal X-ray and chemical analysis.

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Acknowledgments

This work was supported by the Funds of Henan Agricultural University and the Funds of Heilongjiang August First Land Reclamation University, P.R. China.

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Authors and Affiliations

  1. The College of Animal Husbandry and Veterinary, Henan Agricultural University, 450002, Zhengzhou, Henan, People’s Republic of China

    Juan Mo, Su-Mei Zhang & Jian-Hua Liu

  2. College of Life Science and Biotechnology, Heilongjiang August First Land Reclamation University, 163319, Daqing, Heilongjiang, People’s Republic of China

    Wen-Zhong Ge

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  1. Juan Mo
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  2. Su-Mei Zhang
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  4. Jian-Hua Liu
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Correspondence to Juan Mo.

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Mo, J., Zhang, SM., Ge, WZ. et al. Synthesis, Crystal Structure of catena-poly [[4,4′-bipyridine-N,N′-bis[(triphenylphosphine)-copper(I)]-pyridine-2-carbaldehyde azine-N,N′:N″,N′″] bis(tetrafluoroboride)]. J Chem Crystallogr 39, 890–893 (2009). https://doi.org/10.1007/s10870-009-9585-1

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  • DOI: https://doi.org/10.1007/s10870-009-9585-1

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