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A New 3-D Gd(III) Coordination Polymer Constructed with Mixed Aromatic Acid: Synthesis, Structural Characterization and Magnetic Characterization

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Abstract

Using pyridine-2,5-dicarboxylic acid (2,5-pdcH2) and Gd2O3, a new three-dimensional (3D) polymeric complex, [Gd(2,5-pdc)(nic)·H2O] n (1) was synthesized under hydrothermal conditions, in which nic (nicotinate; also named as pyridine-2-carboxylic acid) might have been formed from the 2,5-pdc ligands through the C–C bond cleavage and release of CO2 molecules. The complex crystallizes in monoclinic system, space group P21/c with unit cell parameters a = 9.221(9) Å, b = 14.179(14) Å, c = 10.516(10) Å, β = 95.658(14)°, V = 1,368(2) Å3 and Z = 2. 2,5-pdc ligands bridge gadolinium centers to form the three-dimensional framework featuring hexagonal channels along the axis a which are occupied by bridging nic anions and mono-coordinated water molecules. Magnetic properties have been investigated in the range of 2–300 K reveal that t there is very weak antiferromagnetic exchange between the Gd(III) ions (J = −0.017 cm−1).

Graphical Abstract

Three-dimensional complex [Gd(2,5-pdc)(nic)·H2O] n has been hydrothermally synthesized, in which nic might have been formed from the 2,5-pdc ligands through the C–C bond cleavage with CO2 molecules released. 2,5-pdc ligands bridge lanthanide centers to form the three-dimensional frameworks. The magnetic properties of the compound have also been investigated.

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Acknowledgments

We thank the financial support by the National Natural Science Foundation of China (No. 20771084) and Tianjin Natural Science Foundation (No. 06YFJMJC12700).

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Authors and Affiliations

  1. School of Pharmaceutical Sciences, Tianjin Medical University, 300070, Tianjin, People’s Republic of China

    Chengzhi Xie, Qiji Zhou & Jingyuan Xu

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  1. Chengzhi Xie
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  2. Qiji Zhou
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  3. Jingyuan Xu
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Correspondence to Jingyuan Xu.

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Xie, C., Zhou, Q. & Xu, J. A New 3-D Gd(III) Coordination Polymer Constructed with Mixed Aromatic Acid: Synthesis, Structural Characterization and Magnetic Characterization. J Chem Crystallogr 39, 799–803 (2009). https://doi.org/10.1007/s10870-009-9567-3

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  • DOI: https://doi.org/10.1007/s10870-009-9567-3

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