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Synthesis and Crystal Structure of Three New Metal-Organic Frameworks in the Ln(III)/2,6-Pyridinedicarboxylate System

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Abstract

In this paper, three new metal-organic frameworks, synthesized by hydrothermal technique, are described. The compounds crystallize in triclinic space group P − 1 with cell parameters, respectively equal to (1) [La(H2O)3(dipic)]2(C2O4) · 2H2O a = 7.9990(1) Å, b = 8.3380(4) Å, c = 9.6180(5) Å, α = 98.194(5)°, β = 100.438(3)°, γ = 102.437(3)°, (2) [Eu(H2O)2(C2O4)]2(dipic) · 3H2O a = 8.2170(6) Å, b = 10.5900(8) Å, c = 13.0670(3) Å, α = 93.951(3)°, β = 103.393(5)°, γ = 107.797(6)°, and (3) [Ce3(dipic)3(Hdipic)(SO4)(H2O)3] · 4H2O a = 11.655(1) Å, b = 12.886(1) Å, c = 16.139(2) Å, α = 106.369(8)°, β = 92.90(1)°, γ = 115.787(7)°. They differ by their dimensionality mono-dimensional for (1), tri-dimensional for (2) and bi-dimensional for (3).

Index Abstract

Compound (3) [Ce3(dipic)3(Hdipic)(SO4)(H2O)3] · 4H2O crystallizes in a three dimensional network because of the strong hydrogen bonds and the overlap between some pyridine rings of dipic ligand.

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References

  1. Serpaggi F, Férey G (1998) J Mater Chem 8:2737. doi:10.1039/a802713g

    Article  CAS  Google Scholar 

  2. Batten SR, Robson R (1998) Angew Chem Int Ed 37:1460. doi:10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z

    Article  Google Scholar 

  3. Chirayil T, Zavalij PY, Whittingham S (1998) Chem Mater 10:2629. doi:10.1021/cm980242m

    Article  CAS  Google Scholar 

  4. Ayyappan S, Cheetham AK, Natarajan S, Rao CNR (1998) Chem Mater 10:3746. doi:10.1021/cm980574r

    Article  CAS  Google Scholar 

  5. Li H, Eddaoudi M, O’Keeffe M, Yaghi OM (1999) Nature 402:276. doi:10.1038/46248

    Article  CAS  Google Scholar 

  6. Cheetham AK, Férey G, Loiseau T (1999) Angew Chem Int Ed 38:3268. doi:10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO;2-U

    Article  CAS  Google Scholar 

  7. Reineke TM, Eddaoudi M, O’Keeffe M, Yaghi OM (1999) Angew Chem Int Ed 38:2549. doi:10.1002/(SICI)1521-3773(19990903)38:17<2590::AID-ANIE2590>3.0.CO;2-H

    Article  Google Scholar 

  8. Hagrman PJ, Hagrman D, Zubieta J (1999) Angew Chem Int Ed 38:2638. doi:10.1002/(SICI)1521-3773(19990917)38:18<2638::AID-ANIE2638>3.0.CO;2-4

    Article  Google Scholar 

  9. Reineke TM, Eddaoudi M, Fehr M, Kelley D, Yaghi OM (1999) J Am Chem Soc 121:1651. doi:10.1021/ja983577d

    Article  CAS  Google Scholar 

  10. Férey G (2000) J Solid State Chem 152:37. doi:10.1006/jssc.2000.8667

    Article  Google Scholar 

  11. Choudhury A, Natarajan S, Rao CNR (2000) Chem Eur J 6:1168. doi:10.1002/(SICI)1521-3765(20000403)6:7<1168::AID-CHEM1168>3.3.CO;2-J

    Article  CAS  Google Scholar 

  12. O’Keeffe M, Eddaoudi M, Li H, Reineke M, Yaghi OM (2000) J Solid State Chem 152:3. doi:10.1006/jssc.2000.8723

    Article  Google Scholar 

  13. Férey G (2001) Chem Mater 13:3084. doi:10.1021/cm011070n

    Article  Google Scholar 

  14. Hagrman PJ, Finn R, Zubieta J (2001) Solid State Sci 3:745. doi:10.1016/S1293-2558(01)01186-4

    Article  CAS  Google Scholar 

  15. Rowsell JLC, Yaghi OM (2004) Microporous Mesoporous Mater 73:3. doi:10.1016/j.micromeso.2004.03.034

    Article  CAS  Google Scholar 

  16. Rao CNR (2004) Angew Chem Int Ed 43:1466. doi:10.1002/anie.200300588

    Article  CAS  Google Scholar 

  17. Eddaoudi M, Moler DB, Li H, Chen B, Reineke M, O’Keeffeand M, Yaghi OM (2001) Acc Chem Res 34:319. doi:10.1021/ar000034b

    Article  CAS  Google Scholar 

  18. Trombe JC, Jaud J, Galy J (2005) J Solid State Chem 178:1094. doi:10.1016/j.jssc.2005.01.017

    Article  CAS  Google Scholar 

  19. Rao CNR, Natarajan S, Choudhury A, Neeraj S, Vaidhyanathan R (2001) Acta Crystallogr B 57:1. doi:10.1107/S0108768100017638

    Article  CAS  Google Scholar 

  20. Eddaoudi M, Li H, Reineke T, Fehr M, Kelley D, Groy TL, Yaghi OM (1999) Top Catal 9:105. doi:10.1023/A:1019110622091

    Article  CAS  Google Scholar 

  21. Trollet D, Roméro S, Mosset A, Trombe JC (1997) C R Acad Sci Paris IIb 325:663

    CAS  Google Scholar 

  22. Trollet D, Roméro S, Mosset A, Trombe JC (1998) Polyhedron 17:3977

    CAS  Google Scholar 

  23. Trombe JC, Jaud J (2003) J Chem Crystallogr 33:19. doi:10.1023/A:1021343631792

    Article  CAS  Google Scholar 

  24. Fernandes A, Jaud J, Dexpert-Ghys J, Brouca-Cabarrecq C (2001) Polyhedron 20:2385. doi:10.1016/S0277-5387(01)00841-5

    Article  CAS  Google Scholar 

  25. Brouca-Cabarrecq C, Fernandes A, Jaud J, Costes JP (2002) Inorg Chim Acta 332:54. doi:10.1016/S0020-1693(01)00811-8

    Article  CAS  Google Scholar 

  26. Brouca-Cabarrecq C, Dexpert-Ghys J, Fernandes A, Jaud J, Trombe JC (2008) Inorg Chim Acta 361:2909. doi:10.1016/j.ica.2008.02.053

    Article  CAS  Google Scholar 

  27. Thomas P, Trombe JC (2005) J Chem Crystallogr 30:633. doi:10.1023/A:1011992031111

    Article  Google Scholar 

  28. Costes JP, Dahan F, Donnadieu B, Garcia-Toja J, Laurent JP (2001) Eur J Inorg Chem 363. and references cited therein. doi:10.1002/1099-0682(200102)2001:2<363::AID-EJIC363>3.0.CO;2-A

  29. Mohanu A (2005) Thesis. University Paul Sabatier, Toulouse

  30. Yvon K, Jeitschko W, Parthe E (1977) J Appl Cryst 10:73. doi:10.1107/S0021889877012898

    Article  Google Scholar 

  31. Coppens P (1970) In: Ahmed FR, Hall SR, Huber CP (eds) Crystallographic computing. Munksgaard, Copenhagen, pp 255–270

    Google Scholar 

  32. Blessing RH (1995) Acta Crystallogr A 51:33. doi:10.1107/S0108767394005726

    Article  Google Scholar 

  33. Beurskens PT, Beurskens G, Bosman WP, de Gelder RS, Garcia-Granda S, Gould RO, Smits JMM (1996) DIRDIF96, Program System. Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands

    Google Scholar 

  34. Sheldrick GM (1997) SHELXL97, Program for the crystal structure refinement. University of Göttingen, Germany

    Google Scholar 

  35. Macintyre WM, Verkema MS (1964) J Chem Phys 42:3563. doi:10.1063/1.1725052

    Article  Google Scholar 

  36. Prasad TK, Rajasekharan MV (2005) Inorg Chem Commun 8:1116

    Article  CAS  Google Scholar 

  37. Prasad TK, Sailaja S, Rajasekharan MV (2005) Polyhedron 24:1487. doi:10.1016/j.poly.2005.03.104

    Article  CAS  Google Scholar 

  38. Zhao B, Yi L, Dai Y, Chen XY, Cheng P, Liao DZ, Yan SP, Jiang ZH (2005) Inorg Chem 44:911. doi:10.1021/ic049498m

    Article  CAS  Google Scholar 

  39. Brown ID, Altermatt D (1985) Acta Crystallogr B 41:244. doi:10.1107/S0108768185002063

    Article  Google Scholar 

  40. Ollendorf W, Weigel F (1969) Inorg Nucl Chem Lett 5:263. doi:10.1016/0020-1650(69)80196-0

    Article  Google Scholar 

  41. Michaelides A, Soulika S, Aubry A (1988) Mater Res Bull 23:579. doi:10.1016/0025-5408(88)90166-3

    Article  CAS  Google Scholar 

  42. Hansson E (1970) Acta Chem Scand 24:2969

    Article  CAS  Google Scholar 

  43. Hansson E (1973) Acta Chem Scand 27:823. doi:10.3891/acta.chem.scand.27-0823

    Article  CAS  Google Scholar 

  44. Hamilton WC, Ibers JA (1968) In: Benjamin WA (ed) Hydrogen bonding in solids. Benjamin, New York

    Google Scholar 

Download references

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  1. Centre d’Elaboration de Matériaux et d’Etudes Structurales (CEMES/CNRS), 29 rue Jeanne Marvig, BP 94347, 31055, Toulouse cedex, France

    C. Brouca-Cabarrecq & J. C. Trombe

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  1. C. Brouca-Cabarrecq
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  2. J. C. Trombe
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Correspondence to C. Brouca-Cabarrecq.

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Brouca-Cabarrecq, C., Trombe, J.C. Synthesis and Crystal Structure of Three New Metal-Organic Frameworks in the Ln(III)/2,6-Pyridinedicarboxylate System. J Chem Crystallogr 39, 786–798 (2009). https://doi.org/10.1007/s10870-009-9558-4

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