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Synthesis and Crystal Structure of a New Ion-Pair Complex Based on [Ni(tdas)2]2− Anion and Triphenylphosphinium Cation

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Abstract

A new ion-pair complex, bis(1-benzyltriphenylphosphinium) bis(1,2,5-thiadiazole-3,4-dithiolato)nickelate(II), [BzTPP]2[Ni(tdas)2](1), has been prepared and characterized by elemental analyses, UV, IR, MS spectrum, molar conductivity and single crystal X-ray diffraction. The title complex crystallizes in the triclinic space group P-1, a = 9.098(1) Å, b = 9.666(1) Å, c = 29.573(3) Å, α = 83.81(1)°, β = 81.97(1)°, γ = 78.83(1)°, V = 2,517.5(4) Å3, Z = 2. The unit cell contains two [BzTPP]+ and two halves of [Ni(tdas)2]2− anions in which the anion exhibits a quasi-planar structure. The [BzTPP]+ cation adopts a conformation where four phenyl rings are twisted to the C–C–P reference plane. The weak cation–cation C–H···π, π···π interactions and anion–cation C–H···N hydrogen bonds between the anion and cation play an important role in the stacking and stabilizing of the title complex.

Graphical Abstract

The title new ion-pair complex, bis(1-benzyltriphenylphosphinium) bis(1,2,5-thiadiazole-3,4-dithiolato)nickelate(II), [BzTPP]2[Ni(tdas)2](1), contains two [BzTPP]+ and two halves of [Ni(tdas)2]2− anions in which the weak cation–cation C–H···π, π···π interactions and anion−cation C–H···N hydrogen bonds between the anion and cation play an important role in the stacking and stabilizing of the title complex.

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References

  1. Robertson N, Cronin L (2002) Coord Chem Rev 227:93. doi:10.1016/S0010-8545(01)00457-X

    Article  CAS  Google Scholar 

  2. Canadell E (1999) Coord Chem Rev 185–186:629. doi:10.1016/S0010-8545(99)00015-6

    Article  Google Scholar 

  3. Rovira C (2000) Chem Eur J 6:1723. doi:10.1002/(SICI)1521-3765(20000515)6:10<1723::AID-CHEM1723>3.0.CO;2-Z

    Article  CAS  Google Scholar 

  4. Akutagawa T, Nakamura T (2002) Coord Chem Rev 226:3. doi:10.1016/S0010-8545(01)00432-5

    Article  CAS  Google Scholar 

  5. Coomber AT, Beljonne D, Friend RH, Brédas JL, Charlton A, Robertson N, Underhill AE, Kurmoo M, Day P (1996) Nature 380:144. doi:10.1038/380144a0

    Article  CAS  Google Scholar 

  6. Urichi M, Yakushi K, Yamashita Y, Qin J (1998) J Mater Chem 8:141. doi:10.1039/a704813k

    Article  Google Scholar 

  7. Pullen AE, Faulmann C, Pokhodnya KI, Cassoux P, Tokumoto M (1998) Inorg Chem 37:6714. doi:10.1021/ic980876v

    Article  CAS  Google Scholar 

  8. Hou Y, Zhou JR, Liu XP, Yu LL, Ni CL (2008) Transit Met Chem 33:411. doi:10.1007/s11243-008-9054-2

    Article  CAS  Google Scholar 

  9. Robertson N, Bergemann C, Becher H, Agarwal P, Julian SR, Friend RH, Hatton NJ, Underhill AE, Kobayashi A (1999) J Mater Chem 9:1713. doi:10.1039/a903007g

    Article  CAS  Google Scholar 

  10. Ren XM, Meng QJ, Song Y, Hu CJ, Lu CS, Chen XY, Xue ZL (2002) Inorg Chem 41:5931. doi:10.1021/ic0255860

    Article  CAS  Google Scholar 

  11. Ni ZP, Ren XM, Ma J, Xie JL, Ni CL, Chen ZD, Meng QJ (2005) J Am Chem Soc 127:14330. doi:10.1021/ja050631z

    Article  CAS  Google Scholar 

  12. Xie JL, Ren XM, Song Y, Zou Y, Meng QJ (2002) J Chem Soc, Dalton Trans 2868. doi:10.1039/b201936c

  13. Xie JL, Ren XM, Song Y, Zhang WW, Liu WL, He C, Meng QJ (2002) Chem Commun (Camb) 2346. doi:10.1039/b205441h

  14. Ni CL, Dang DB, Song Y, Gao S, Li YZ, Ni ZP, Tian ZF, Wen LL, Meng QJ (2004) Chem Phys Lett 396:353. doi:10.1016/j.cplett.2004.08.060

    Article  CAS  Google Scholar 

  15. Ni CL, Dang DB, Li YZ, Gao S, Ni ZP, Tian ZF, Meng QJ (2005) J Solid State Chem 178:100. doi:10.1016/j.jssc.2004.11.002

    Article  CAS  Google Scholar 

  16. Ni CL, Yu LL, Yang LM (2006) Inorg Chim Acta 359:1383. doi:10.1016/j.ica.2005.12.050

    Article  CAS  Google Scholar 

  17. Ni CL, Song Y, Meng QJ (2006) Chem Phys Lett 419:351. doi:10.1016/j.cplett.2005.11.103

    Article  CAS  Google Scholar 

  18. Ren XM, Meng QJ, Song Y, Lu CS, Hu CJ (2002) Inorg Chem 41:5686. doi:10.1021/ic0111637

    Article  CAS  Google Scholar 

  19. Xie JL, Ren XM, Gao S, Zhang WW, Li YZ, Lu CS, Ni CL, Liu WL, Meng QJ, Yao YG (2003) Eur J Inorg Chem 2393. doi:10.1002/ejic.200300108

  20. Hawkins I, Underhill AE (1990) J Chem Soc Chem Comm 1593

  21. Dyachenko OA, Konovalikhin SV, Kotov AI, Shilov GV, Yagubskii EB, Faulmann C, Cassoux P (1993) J Chem Soc Chem Comm 508

  22. Awagn K, Okuno T, Maruyama Y, Kobayashi A, Kobayashi H, Schenk S, Underhill AE (1994) Inorg Chem 33:5598. doi:10.1021/ic00102a039

    Article  Google Scholar 

  23. Okuno T, Kuwamoto K, Fujita W, Awaga K, Nakanishi W (2003) Polyhedron 14–17:2311. doi:10.1016/S0277-5387(03)00214-6

    Article  Google Scholar 

  24. Curreli S, Deplano P, Mercuri ML, Pilia L, Serpe A, Schlueter JA, Whited MA, Geiser U, Coronado E, Gómez-García CJ, Canadell E (2004) Inorg Chem 43:2049. doi:10.1021/ic035079y

    Article  CAS  Google Scholar 

  25. Wolmershauser G, Johann R (1989) Angew Chem Int Ed Engl 28:920. doi:10.1002/anie.198909201

    Article  Google Scholar 

  26. Bulgarevich SB, Bren DV, Movshovic DY, Finocchiaro P, Failla S (1994) J Mol Struct 317:147. doi:10.1016/0022-2860(93)07862-Q

    Article  CAS  Google Scholar 

  27. SHELXTL Version 5.10. Structure Determination Software Programs, Bruker Analytical X-ray Systems Inc. Madison, Wisconsin, USA (2000)

  28. Johnson MK (2004) Vibrational spectra of dithiolene complexes in dithiolene chemistry, progress in inorganic chemistry. Wiley Inc, New York

    Google Scholar 

  29. Geary WJ (1971) Coord Chem Rev 7:81. doi:10.1016/S0010-8545(00)80009-0

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank the Science and Technology Project (No.2008B080703005) from Guangdong Science and Technology Department and the President’s Science Foundation of South China Agricultural University (No.2008X015) for financial support of this work.

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Authors and Affiliations

  1. Department of Applied Chemistry, Centre of Inorganic Functional Materials, College of Science, South China Agricultural University, 510642, Guangzhou, People’s Republic of China

    Hong-rong Zuo, Jun Tian, Xing Chen, Qian Huang, Jia-rong Zhou, Xiao-ping Liu & Chun-lin Ni

  2. School of Chemical Engineering and Phamacy, Wuhan Institute of Technology, 430073, Wuhan, People’s Republic of China

    Xue-lei Hu

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  1. Hong-rong Zuo
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  2. Jun Tian
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  3. Xing Chen
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Correspondence to Chun-lin Ni.

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Zuo, Hr., Tian, J., Chen, X. et al. Synthesis and Crystal Structure of a New Ion-Pair Complex Based on [Ni(tdas)2]2− Anion and Triphenylphosphinium Cation. J Chem Crystallogr 39, 698–701 (2009). https://doi.org/10.1007/s10870-009-9557-5

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