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Synthesis, Characterization and X-ray Structures of 2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) and its Zinc(II) Complex

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Abstract

2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) Ǻ, b = 16.328(2) Ǻ, c = 8.2670(11) Ǻ, β = 91.869(9)°, while the zinc(II) complex crystallizes in the orthorhombic crystal system, space group Pbcn, with cell parameters a = 14.5927(3) Ǻ, b = 9.6502(2) Ǻ, c = 20.5610(5) Ǻ. The metal center is seven-coordinate, with an approximate pentagonal bipyramidal configuration of the chelating ligand and two apically coordinated DMSO molecules.

Graphical Abstract

X-ray crystallographic study on the [2,6-diacetylpyridine—bis(benzenesulfonylhydrazonato-κ5 N′N′′N′′′O′O′′)]bis(dimethyl sulfoxide-κO)zinc(II) (Fig. 1) shows that the complex is a seven-coordinate, with an approximate pentagonal bipyramidal configuration where the ligand coordinates to the zinc(II) ion as a pentadentate chelate via the pyridine nitrogen atom, the two azomethine nitrogen atoms and the two sulfonyl oxygen atoms.

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Fig. 1
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Acknowledgments

The authors would like to thank Ministry of Higher Education (MOHE) and University of Malaya for the financial support (Science Fund Grant 12-02-03-2051 and PJP FS 350/2008A).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

    Juahir Yusnita, Subramaniam Puvaneswary, Mahmood Ameen Abdulla, Ward T. Robinson & Hapipah Mohd Ali

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  1. Juahir Yusnita
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  2. Subramaniam Puvaneswary
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  3. Mahmood Ameen Abdulla
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  5. Hapipah Mohd Ali
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Correspondence to Hapipah Mohd Ali.

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Yusnita, J., Puvaneswary, S., Abdulla, M.A. et al. Synthesis, Characterization and X-ray Structures of 2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) and its Zinc(II) Complex. J Chem Crystallogr 39, 615–618 (2009). https://doi.org/10.1007/s10870-009-9540-1

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