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[KCl3{H2dabco}]: A Unique 3-D Charge-Assisted Hydrogen-Bonded Hybrid Network of Anionic KCl3 Chains and Organic Cations

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Abstract

The 3-D hybrid network [KCl3{H2dabco}] resulted from the assemblage of KCl and [{H2dabco}Cl2] (1,4-diazabicyclo[2.2.2]octane) in H2O. The compound crystallizes in the trigonal space group R-3c with a = b = 16.0437(2) Å, and c = 22.3094(2) Å. The structure consists in polymeric chains of anionic {KCl3}2− linked to {H2dabco}2+ units by hydrogen bonds. Each organic cation establishes such charge-assisted H···Cl interactions with two inorganic arrays leading to a 3-D network.

Index Abstract

Assemblage of KCl and [{H2dabco}Cl2] (1,4-diazabicyclo[2.2.2]octane) in H2O resulted in a 3-D hybrid network of inorganic {KCl3}2− chains H-bonded to bridging organic cations.

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Acknowledgment

The authors are grateful to Dr. Neil Brooks, from Oxford Diffraction, for technical assistance.

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Authors and Affiliations

  1. CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, 31077, Toulouse, France

    Franck Thétiot, Isabelle Sasaki, Carine Duhayon & Jean-Pascal Sutter

  2. Université de Toulouse, UPS, INPT, LCC, 31077, Toulouse, France

    Franck Thétiot, Isabelle Sasaki, Carine Duhayon & Jean-Pascal Sutter

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  1. Franck Thétiot
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  2. Isabelle Sasaki
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  3. Carine Duhayon
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  4. Jean-Pascal Sutter
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Correspondence to Jean-Pascal Sutter.

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Thétiot, F., Sasaki, I., Duhayon, C. et al. [KCl3{H2dabco}]: A Unique 3-D Charge-Assisted Hydrogen-Bonded Hybrid Network of Anionic KCl3 Chains and Organic Cations. J Chem Crystallogr 39, 225–227 (2009). https://doi.org/10.1007/s10870-008-9511-y

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  • DOI: https://doi.org/10.1007/s10870-008-9511-y

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