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A Novel Keggin-Type Aluminotungstate Dimeric Compound: H3.5[Ni(2,2′-bipy)3]3{[AlW VI10 W V2 O40Ni(2,2′-bipy)2(H2O)]2Na0.5}

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Abstract

A novel dimeric compound H3.5[Ni(2,2′-bipy)3]3{[AlW12O40Ni(2,2′-bipy)2(H2O)]2Na0.5} prepared by the hydrothermal method consists of a {[AlW12O40Ni(2,2′-bipy)2(H2O)]2Na0.5}9.5− heteropolyanion, and in the anion, two reduced Keggin heteropolyanions [AlWVI 10W V2 O40]7− are bridged via Na coordination ion by means of an O–Na1–O linkage (O atoms from the surface bridging oxygen atoms of [AlWVI 10W V2 O40]7−) and two Ni coordination ions are linked to the Na1 square planar moiety by making use of Ni–Ow–Na1–Ow–Ni bridges. The crystal belongs to the monoclinic-space group C2/c, a = 46.592(9), b = 14.306(3), c = 25.967(5) Å, β = 90.14(3)°, V = 17308(6) Å3, Z = 4, D c  = 3.116 Mg/m3.

Index Abstract

A novel dimeric compound H3.5[Ni(2,2′-bipy)3]3{[AlW12O40Ni(2,2′-bipy)2(H2O)]2Na0.5} prepared by the hydrothermal method consists of a {[AlW12O40Ni(2,2′-bipy)2(H2O)]2Na0.5}9.5− heteropolyanion, and in the anion, two reduced Keggin heterpolyanions [AlWVI 10WV 2O40]7− are bridged via Na coordination ion by means of an O–Na1–O linkage (O atoms from the surface bridging oxygen atoms of [AlWVI 10WV 2O40]7−) and two Ni coordination ions are linked to the Na1 square planar moiety by making use of Ni7–Ow7–Na17–Ow7–Ni bridges.

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Acknowledgments

The work was supported by the National Doctoral Research Foundation of China, Henan Innovation Project for University Prominent Research Talents, the Institute of Education of Henan Province and Natural Science Foundation of Henan Province. We gratefully acknowledge financial support from the Natural Science Foundation of Henan Province.

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  1. Institute of Molecule and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Minglun Street 85#, Kaifeng, 475001, P. R. China

    Jing-Ping Wang, Yue Shen, Dong-Qin Bi & Jing-Yang Niu

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  1. Jing-Ping Wang
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  2. Yue Shen
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Correspondence to Jing-Ping Wang.

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Wang, JP., Shen, Y., Bi, DQ. et al. A Novel Keggin-Type Aluminotungstate Dimeric Compound: H3.5[Ni(2,2′-bipy)3]3{[AlW VI10 W V2 O40Ni(2,2′-bipy)2(H2O)]2Na0.5}. J Chem Crystallogr 39, 251–255 (2009). https://doi.org/10.1007/s10870-008-9463-2

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