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Synthesis and Crystal Structure of a Novel Double-Chain Coordination Polymer [Zn2(bipy)2(btec)(H2O)2]n (bipy = 2,2′-bipyridine; btec = 1,2,4,5-benzenetetracarboxylate)

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Abstract

A novel aromatic polycarboxylate polymer, [Zn2(bipy)2(btec)(H2O)2]n (1), has been synthesized and structurally characterized by the single crystal X-ray diffraction. Compound 1 belongs to the triclinic crystal system, space group P-1; a = 7.7449(6) Å, b = 8.9286(8) Å, c = 10.7422(8) Å, α = 80.95(1)°, β = 70.21(1)°, γ = 78.14(1)°, V = 680.93(10) Å3, Z = 2. The coordination geometry of Zn(II) atom is distorted trigonal bipyramidal with two nitrogen atoms of one 2,2′-bipy group, two oxygen atoms from two different btec ligands, and one water. The 16-membered rings are alternately arranged forming an infinite 1-D double-chain structure. A 3-D network was constructed by interlayer C···H–O, O···H–O hydrogen bonds and π–π stacking interactions. Compound 1 exhibits fluorescence at room temperature in the solid state.

Graphical Abstract

A 1-D double-chain aromatic polycarboxylate polymer, [Zn2(bipy)2(btec)(H2O)2]n (1), has been synthesized and structurally characterized by the single crystal X-ray diffraction. A 3-D network was constructed by intermolecular C···H–O, O···H–O hydrogen bonds and π–π stacking interactions. Compound 1 exhibits fluorescence at room temperature in the solid state.

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Acknowledgments

We are indebted to the National Natural Science Foundation of China (No 20471026) and Natural Science Foundation of Henan province (No 0511022600) for the financial support.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan, 471022, People’s Republic of China

    Jingcai Yao, Yange Li & Xuelan Mei

  2. Henan Radio and Television University, Zhengzhou, Henan, 450008, People’s Republic of China

    Lingli Wu

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  1. Jingcai Yao
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  2. Lingli Wu
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  4. Xuelan Mei
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Correspondence to Jingcai Yao.

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Yao, J., Wu, L., Li, Y. et al. Synthesis and Crystal Structure of a Novel Double-Chain Coordination Polymer [Zn2(bipy)2(btec)(H2O)2]n (bipy = 2,2′-bipyridine; btec = 1,2,4,5-benzenetetracarboxylate). J Chem Crystallogr 39, 246–250 (2009). https://doi.org/10.1007/s10870-008-9461-4

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