Abstract
A novel thiazole-based iridium (III) complex (iridium(III)bis(2-p-tolyl-benzothiazolato-N,C2)(acetylacetonate)) has been prepared and fully characterized by EA, IR, 1H-NMR and MS. The molecular structure of the complex has been determined by single crystal X-ray diffraction analysis. The iridium (III) center adopts a distorted octahedral geometry with cis-O–O, cis-C–C, and trans-N–N chelate disposition. The complex crystallizes in the orthorhombic Pbca space group with cell parameters a = 10.1388(7) Å, b = 18.3565(12) Å, c = 31.021(2) Å, α = β = γ = 90 ° and Z = 8. The electronic absorption and emission spectra of this complex have been investigated.
Index Abstract
A novel thiazole-based phosphorescent iridium (III) complex (iridium(III) bis (2-p-tolyl-benzothiazolato-N,C2)(acetylacetonate)) has been prepared and fully characterized by EA, IR, 1H-NMR, MS and X-ray diffraction analysis.
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Acknowledgments
We are grateful for financial support from the National Natural Science Foundation of China (Project Nos. 20702064) and Natural Science Foundation of South-Central University for Nationalities (grant Nos. YZZ07007).
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Chen, L., Qu, X. Synthesis, Characterization and Crystal Structure of Iridium(III)bis(2-p-tolyl-benzothiazolato-N,C2)(acetylacetonate). J Chem Crystallogr 39, 241–245 (2009). https://doi.org/10.1007/s10870-008-9452-5
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DOI: https://doi.org/10.1007/s10870-008-9452-5