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catena-Bis(μ-chloro)-(κ-O, κ-N-{2-thenoylhydrazine})-cadmium(II), a Novel Cadmium Coordination Polymer

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Abstract

The title compound, [CdCl2(C5H6N2OS)] n , crystallizes in the polar space group R3c with the crystal cell parameters a = 23.363(3) Å, c = 9.5560(19) Å, V = 4,478.4(13) Å3 and Z = 18. Each cadmium is coordinated to four bridging chloro ligands, the carbonyl oxygen and the terminal nitrogen atom of a 2-thenoylhydrazine ligand. The chelating coordination by the latter moiety implies a distorted cis octahedral arrangement around the metal center. The resulting helical polymer chains in the direction of the crystallographic c axis are cross-linked by the N–H···O hydrogen bonds to a three-dimensional network.

Index Abstract

catena-Bis(μ-chloro)-(κ-O, κ-N-{2-thenoylhydrazine})-cadmium(II) crystallizes in the polar space group R3c as a helical polymer which expands along the c axis.

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Acknowledgments

This work is supported by National Nature Science Foundation of China (20571012) and Nature Science Foundation of Beijing (2042013).

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Authors and Affiliations

  1. College of Chemistry, Beijing Normal University, Beijing, 100875, People’s Republic of China

    Lili Cao & Qi Li

  2. Institut fuer Anorganische Chemie, RWTH Aachen, Aachen, 52074, Germany

    Ulli Englert

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  1. Lili Cao
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  2. Qi Li
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  3. Ulli Englert
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Correspondence to Qi Li.

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Cao, L., Li, Q. & Englert, U. catena-Bis(μ-chloro)-(κ-O, κ-N-{2-thenoylhydrazine})-cadmium(II), a Novel Cadmium Coordination Polymer. J Chem Crystallogr 38, 833–836 (2008). https://doi.org/10.1007/s10870-008-9418-7

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  • DOI: https://doi.org/10.1007/s10870-008-9418-7

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