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The Synthesis and Crystal Structure of 5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl Acid

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Abstract

5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl acid 3 was synthesized from 1-aminonaphthalene. The yielded product 3 was investigated with X-ray crystallographic, NMR, MS and IR techniques. Compound 3, C14H11N3O2, Mr = 253.26, crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 10.068(2), b = 12.353(2), c = 20.102(4) Å, V = 2500.1(8) Å3, Z = 8, Dx = 1.346 Mgm-3. The final R was 0.0474. The molecular packing is stabilized by intermolecular O–H···N interactions.

Index Abstract

5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl acid 3 was synthesized from 1-aminonaphthalene. The yielded product 3 was investigated with X-ray crystallographic, NMR, MS and IR techniques. Compound 3, C14H11N3O2, Mr = 253.26, crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 10.068(2), b = 12.353(2), c = 20.102(4) Å, α = β = γ = 90.00º. V = 2,500.1(8) Å3, Z = 8, Dx = 1.346 Mgm−3. The final R was 0.0474. The molecular packing is stabilized by intermolecular O–H···N interactions.

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Acknowledgments

The authors would like to acknowledge Lanzhou University SKLAOC for their support.

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Authors and Affiliations

  1. State Key Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu, 730000, People’s Republic of China

    Shi-Qiang Liu & Heng-Shan Dong

  2. College of Science and Engineering, Gansu Association University, Lanzhou, Gansu, 730000, China

    Bin Quan & Hong-Ru Dong

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  1. Shi-Qiang Liu
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  2. Bin Quan
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  3. Hong-Ru Dong
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  4. Heng-Shan Dong
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Correspondence to Heng-Shan Dong.

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Liu, SQ., Quan, B., Dong, HR. et al. The Synthesis and Crystal Structure of 5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl Acid. J Chem Crystallogr 39, 87–90 (2009). https://doi.org/10.1007/s10870-008-9408-9

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  • DOI: https://doi.org/10.1007/s10870-008-9408-9

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