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Crystal Structure of 4,7-Dichloro-1,2,3,5,6,8-hexakis-(4-methoxy-phenylsulfanyl)-acenaphthylene

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Abstract

The title compound was prepared from the reaction of perchloroacenaphthylene with an excess of sodium salt of 4-methyloxythiophenol in toluene/ethanol (1:1) solvent and structurally characterized by single-crystal X-ray diffraction. The compound crystallizes in the Monoclinic space group P2(1) with the parameters: a = 10.351(1) Å, b = 20.453(3) Å, c = 12.1837(16) Å, β = 105.584(3)°, V = 2484.5(6) Å3, with Z = 2 formula units.

Graphical Abstract

The title compound 4,7-dichloro-1,2,3,5,6,8-hexakis-(4-methoxy-phenylsulfanyl)-acenaphthylene was synthesized from perchloroacenaphthylene C 12 Cl 8 with an excess of 4-methoxybenzene thiolate in toluene/ethanol (1:1)

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Acknowledgements

This work was supported by National Natural Science Foundation of China (Grant No. 20601022, 20721001, J0630429) and National Basic Research Program of China (973 Program: 2007CB815301).

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Authors and Affiliations

  1. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005, P.R. China

    Shun-Liu Deng, Sa Li, Rong-Bin Huang & Lan-Sun Zheng

  2. The Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, Fujian, 361005, P.R. China

    Lan-Sun Zheng

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  1. Shun-Liu Deng
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  2. Sa Li
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  3. Rong-Bin Huang
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  4. Lan-Sun Zheng
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Correspondence to Shun-Liu Deng.

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Deng, SL., Li, S., Huang, RB. et al. Crystal Structure of 4,7-Dichloro-1,2,3,5,6,8-hexakis-(4-methoxy-phenylsulfanyl)-acenaphthylene. J Chem Crystallogr 38, 679–683 (2008). https://doi.org/10.1007/s10870-008-9373-3

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  • DOI: https://doi.org/10.1007/s10870-008-9373-3

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