Abstract
The salt tris-(N–N dimethyl benzylammonium)-hexachlorobismuthate(III) crystallizes in the triclinic system P1 with unit cell parameters: a = 9.0300(12), b = 9.9220(3), c = 19.575(2) Å, α = 79.955(5), β = 89.952(2), γ = 88.108(6)°, V = 1726.0(3) Å3, Z = 2. The examination of the structure shows an alternate stacking of inorganic layers of hexachlorobismuthate(III) anions and organic layers of [C6H5CH2NH(CH3)2]+ cations parallel to the a-axis. The cohesion forces of the packing of N–N dimethyl benzylammonium units in the layer and between two adjacent layers are provided by hydrogen bonds (N–H⋯Cl) and van der Waals contacts.
Index Abstract
The examination of the structure shows a layer arrangement parallel to the a-axis: planes of octahedral anions [BiCl6]3− alternate with planes of [C6H5CH2NH(CH3)2]+ cations (Fig. 3). The cohesion forces of the packing of the N–N dimethyl benzylammonium units in the layer and between two adjacent layers are provided by hydrogen bonds (N–H⋯Cl) and van der Waals contacts.
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Nasri, S., Zouari, F. & El Feki, H. Synthesis and Crystal Structure of Tris-(N–N dimethyl benzylammonium)-hexachlorobismuthate(III). J Chem Crystallogr 38, 729–732 (2008). https://doi.org/10.1007/s10870-008-9367-1
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DOI: https://doi.org/10.1007/s10870-008-9367-1