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Synthesis and Crystal Structure of [Mn(H2O)(tptz)(CH3COO)][N(CN)2] · 2H2O (tptz = 2,4,6-tris-(2-pyridyl)-1,3,5-triazine)

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Abstract

The manganese complex [Mn(H2O)(tptz)(CH3COO)][N(CN)2] · 2H2O 1 (tptz = 2,4,6-tris-(2-pyridyl)-1,3,5-triazine) has been synthesized and structurally characterized by X-ray diffraction, element analysis and IR spectrum. It crystallizes in the monoclinic space group C2/c, a = 14.6898(1) Å, b = 13.4002(9) Å, c = 26.865(2) Å, β = 99.672(3)°, V = 5213.0(7) Å3, Z = 8. The number of coordination around Mn(II) atom is seven; it is coordinated equatorially by three nitrogen atoms from tptz, and two oxygen atoms from acetate, and axially by one nitrogen atom of dicyanamide and one coordinated water molecule. The crystal structure is stabilized through hydrogen bonds.

Index Abstract

The title compound, [Mn(H2O)(tptz)(CH3COO)][N(CN)2] · 2H2O was synthesized by the treatment of 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz) and Mn(OAc)2 · 4H2O, with NaN(CN)2 and its crystal structure determined. Single crystal X-ray diffraction analysis reveals that the number of coordination around Mn(II) atom is seven.

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Acknowledgements

This work was supported by the NNSFC (No: 20361004 and 20561004), NSF of Yunnan Province (No: 2003E0012M, 2004E0008M and 2003RC13).

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Authors and Affiliations

  1. School of Chemical Science and Engineering, Key Laboratory of Natural Resources and Medicinal Chemistry, Yunnan University, Kunming, 650091, People’s Republic of China

    Meisu Zhang, Ruibin Fang & Qihua Zhao

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  1. Meisu Zhang
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  2. Ruibin Fang
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  3. Qihua Zhao
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Correspondence to Qihua Zhao.

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Zhang, M., Fang, R. & Zhao, Q. Synthesis and Crystal Structure of [Mn(H2O)(tptz)(CH3COO)][N(CN)2] · 2H2O (tptz = 2,4,6-tris-(2-pyridyl)-1,3,5-triazine). J Chem Crystallogr 38, 601–604 (2008). https://doi.org/10.1007/s10870-008-9352-8

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