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Synthesis and Crystal Structure of La(NO2)(SO4)(H2O)

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Abstract

Single crystals of new open-framework lanthanide sulphate nitrite La(NO2)(SO4)(H2O) has been synthesized, in the presence of 2,6-diformyl-4-chlorophenol. His structure has been determined by X-ray diffraction data: the complex crystallizes in the tetragonal system, space group P43, with a = 7.0028(2) (Å), b = 7.0028(2) (Å), c = 11.8341(4) Å, V = 580.34(3) Å3, Z = 4, D c = 3.582 Mg m−3. The three-dimensional (3D) framework of this compound is built up by the linkages of lanthanide atoms and the oxygen atoms of the sulphate \( {\left( {{\text{SO}}^{{{\text{2}} - }}_{{\text{4}}} } \right)} \) and nitrite \( {\left( {{\text{NO}}^{ - }_{{\text{2}}} } \right)} \) groups. The lanthanum atom is 9-fold coordinated. The structure is unfamiliar in lanthanide chemistry and this compound represents the first example of nitrite lanthanide sulphate complex.

Graphical Abstract

An unfamiliar structure in lanthanide chemistry represented by the first example of nitrite lanthanide sulphate complex is described.

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Authors and Affiliations

  1. Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal

    M. Diallo, M. Diop, P. M. Haba, M. Gaye & A. S. Sall

  2. Département de Chimie, Faculté des Sciences, Université de Nouakchott, Nouakchott, Mauritania

    A. H. Barry

  3. Laboratoire DECMET, UMR CNRS 7513 Université Louis Pasteur 4, rue Blaise Pascal, 67000, Strasbourg, France

    C. Beghidja & R. Welter

Authors
  1. M. Diallo
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  2. M. Diop
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  3. P. M. Haba
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  4. M. Gaye
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  5. A. S. Sall
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  6. A. H. Barry
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  7. C. Beghidja
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  8. R. Welter
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Correspondence to M. Gaye.

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Diallo, M., Diop, M., Haba, P.M. et al. Synthesis and Crystal Structure of La(NO2)(SO4)(H2O). J Chem Crystallogr 38, 475–478 (2008). https://doi.org/10.1007/s10870-008-9349-3

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  • DOI: https://doi.org/10.1007/s10870-008-9349-3

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