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Synthesis and Crystal Structure of 5,7,12,13b,13c,14-Hexahydro-1,4,-dibromo-8,11-dimethoxy-13b,13c-bis(ethoxycarbonyl)-6H,13H-5a,6a,12a,13a-tetra azbenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

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Abstract

The title compound has been synthesized by the reaction of 4 with 1,4-dimethoxybenzene. The yielded product 5 was investigated with X-ray crystallographic, NMR, EI-MS, and IR techniques. The crystal belongs to a monoclinic system, space group P21/c with unit cell parameters a = 12.7790(17) Å, b = 21.565(3) Å, c = 12.2544(16) Å, α = 90°, β = 107.014(2)°, γ = 90°, V = 3229.3(7) Å3, Z = 4, Dc = 1.661, Mr = 807.32, μ = 2.732 mm−1, F(000) = 1632, R1 = 0.0540 and wR2 = 0.0989.

Index Abstract

Dimeric aggregates are formed through hydrogen bond and offset π–π stacking interactions.

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Acknowledgments

The authors would like to express their thanks to Xianggao Meng for performing the X-ray crystallographic measurements. This study was financially supported by Innovative Team of Huangshi Institute of Technology.

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Authors and Affiliations

  1. Key Lab of Pesticide & Chemical Biology, Ministry of Education, Chemistry Department of Central China Normal University, Wuhan, 430079, People’s Republic of China

    Zhiguo Wang, Yuzhou Wang, Guodong Yin & Anxin Wu

  2. School of Chemical and Materials Engineering, Huangshi Institute of Technology, Huangshi, 435003, People’s Republic of China

    Zhiguo Wang

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  1. Zhiguo Wang
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  2. Yuzhou Wang
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  4. Anxin Wu
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Correspondence to Anxin Wu.

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Wang, Z., Wang, Y., Yin, G. et al. Synthesis and Crystal Structure of 5,7,12,13b,13c,14-Hexahydro-1,4,-dibromo-8,11-dimethoxy-13b,13c-bis(ethoxycarbonyl)-6H,13H-5a,6a,12a,13a-tetra azbenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione. J Chem Crystallogr 38, 591–594 (2008). https://doi.org/10.1007/s10870-008-9348-4

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  • DOI: https://doi.org/10.1007/s10870-008-9348-4

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