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Synthesis and Crystal Structure of N′-(6-Chloropyridin-3-formyl)-N-t-Butyl Urea

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Abstract

The crystal structure of N′-(6-chloropyridin-3-formyl)-N-t-butyl urea, C11H14ClN3O2, has been established, and which belongs to monoclinic crystal system, space group Pn with unit cell dimensions a = 9.335(3) Å, b = 12.715(3) Å, c = 21.813(6) Å, β = 95.417(6)°, V = 2577.6(12) Å3 and Z = 8. An intramolecular N–H···O hydrogen bond forms a six-membered ring in the central part of the molecule. Both two N–H atoms of single unit participate in intermolecular hydrogen bonds and an intramolecular hydrogen bond, respectively.

Index Abstract

The crystal structure ofN′-(6-chloropyridin-3-formyl)-N-t-butyl urea, C11H14ClN3O2, has been established, and which belongs to monoclinic crystal system withZ = 8, space group Pn.

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Scheme 1
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Fig. 2

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Acknowledgement

This work was sponsored by National and Shanghai Key Technologies R&D Programs, the Nos. are 2004BA308A22-8 and 034319253, respectively.

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Authors and Affiliations

  1. Institute of Pesticides and Pharmaceuticals, East China University of Science and Technology, Shanghai, 200237, P.R. China

    Shaoyong Ke

  2. Department of Chemistry, Shanghai Normal University, Shanghai, 200234, P.R. China

    Sijia Xue

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  1. Shaoyong Ke
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  2. Sijia Xue
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Correspondence to Shaoyong Ke.

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Ke, S., Xue, S. Synthesis and Crystal Structure of N′-(6-Chloropyridin-3-formyl)-N-t-Butyl Urea. J Chem Crystallogr 38, 467–470 (2008). https://doi.org/10.1007/s10870-008-9345-7

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  • DOI: https://doi.org/10.1007/s10870-008-9345-7

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