Skip to main content
SpringerLink
Log in

Crystal Structure and Magnetic Properties of a Novel Octa-coordinated Manganese(II) Complex

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The self-assembly and structural characterization of the new manganese(II) [MnL 2](ClO4)2(CH3OH)0.5 (1) complex has been achieved. The crystallographic data for the complex 1: Orthorhombic Pbca , a = 16.287(2) Å, b = 21.293(2)Å, c = 32.718(3) Å, V = 11,347(2) Å3, Z = 8. The two polydentate ligands strand intertwined each other and around the manganese(II) ions forming a mononuclear complex. The Mn(II) ion is eight-coordinated with the eight donor nitrogen atoms of two ligands to form a distorted square antiprismatic coordination geometry. The magnetic properties investigation indicates that there is a weak antiferromagnetic exchange coupling between the Mn(II) ions of the complex.

Index Abstract

An octa-coordinated Mn(II) complex which exhibits a distorted square antiprismatic coordination geometry has been achieved by using a bisbidentate Schiff-base ligand.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. (a) Lehn JM (1995) Supramolecular chemistry, concepts and perspectives. VCH, Weinheim; (b) Atwood JL, Davies JED, MacNicol DD, Vogtle F, Lehn JM (eds) (1996) Comprehensive supramolecular chemistry. Pergamon, Oxford, 9:165

  2. Schultheiss N, Powell DR, Bosch E (2003) Inorg Chem 42:8886

    Article  CAS  Google Scholar 

  3. (a) Slagt VF, Kamer PCJ, van Leeuwen PWNM, Reek JNH (2004) J Am Chem Soc 126:1526; (b) Hogg L, Leigh DA, Lusby PJ, Morelli A, Parsons S, Wong JKY (2004) Angew Chem Int Ed 43:1218

    Google Scholar 

  4. (a) Bai Y, Guo D, Duan CY, Dang DB, Pang KL, Meng QJ (2004) Chem Commun 186; (b) Scarpellini M, Neves A, Hörner R, Bortoluzzi AJ, Szpoganics B, Zucco C, Silva RAN, Drago V, Mangrich AS, Ortiz WA, Passos WAC, de Oliveira MCB, Terenzi H (2003) Inorg Chem 42:8353

  5. (a) Benny PB, Barnes CL, Piekarski PM, Lydon JD, Jurisson SS (2003) Inorg Chem 42:6519; (b) Arnold PL, Blake AJ, Wilson C, Love JB (2004) Inorg Chem 43:8206

  6. (a) Shimazaki Y, Tani F, Fukui K, Naruta Y, Yamauchi O (2004) J Am Chem Soc 126:13236; (b) Wagler J, Doert T, Roewer G (2004) Angew Chem Int Ed 43:2441

    Google Scholar 

  7. (a) Nitschke JR (2004) Angew Chem Int Ed 43:3073; (b) Klein H-F, Camadanli S, Beck R, Leukel D, Flörke U (2005) Angew Chem Int Ed 44:975; (c) Oh M, Carpenter G, Sweigart DA (2004) Acc Chem Res 37:1

  8. (a) Pal PK, Chowdhury S, Drew MGB, Datta D (2000) New J Chem 24:931; (b) Chowdhury S, Iveson PB, Drew MGB, Tocher DA, Datta D (2003) New J Chem 27:193

  9. Lόpez-Torres E, Mendiola MA, Pastor CJ, Pérez BS (2004) Inorg Chem 43:5222

    Article  Google Scholar 

  10. Halper SR, Cohen SM (2005) Inorg Chem 44:486

    Article  CAS  Google Scholar 

  11. (a) Bretonnière Y, Mazzanti M, Pécaut J, Olmstead MM (2002) J Am Chem Soc 124:9012; (b) Gao EQ, Bai SQ, Yue YF, Wang ZM, Yan CH (2003) Inorg Chem 42:3642

  12. (a) Vaira MD, Mani F, Stoppioni P (1992) J Chem Soc Dalton Trans 1127; (b) Bu XH, Chen W, Mu LJ, Zhang ZH, Zhang RH, Clifford T (2000) Polyhedron 2095

  13. (a) Fang CJ, Duan CY, Guo D, He C, Meng QJ, Wang ZM, Yan CH (2001) Chem Commun 2540; (b) Guo D, Qian CQ, Duan CY, Pang KL, Meng QJ (2003) Inorg Chem 42:2024. (c) Bai Y, Dang DB, Duan CY, Song Y, Meng QJ (2005) Inorg Chem 44:5972

  14. SMART and SAINT (1996) Area detector control and integration software. Siemens Analytical X-ray Systems, Inc., Madison

  15. Sheldrick GM (1997) SHELXTL V5.1, software reference manual. Bruker, AXS, Inc., Madison

    Google Scholar 

  16. Bennett MV, Long JR (2003) J Am Chem Soc 125:2394

    Article  CAS  Google Scholar 

  17. (a) Guo D, He C, Duan CY, Qian CQ, Meng QJ (2002) New J Chem 26:796; (b) Desiraju GR (1995) Angew Chem Int Ed 34:2311

Download references

Acknowledgment

We are grateful for financial support from the National Natural Science Foundation of China (No. 20701012), the Foundation of the Education Ministry of China (No. 207068) and the Education Department of Henan Province of China (No. 2007150003, 2007150011).

Author information

Authors and Affiliations

  1. Molecular and Crystal Engineering Institute, School of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, P.R. China

    Dongbin Dang & Yan Bai

  2. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P.R. China

    Chunying Duan

Authors
  1. Dongbin Dang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yan Bai
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chunying Duan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yan Bai.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dang, D., Bai, Y. & Duan, C. Crystal Structure and Magnetic Properties of a Novel Octa-coordinated Manganese(II) Complex. J Chem Crystallogr 38, 557–560 (2008). https://doi.org/10.1007/s10870-008-9335-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-008-9335-9

Keywords

Search

Navigation