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Synthesis, Crystal Structure of a New Co(II) Complex with Pyrazine-2,3,5,6-tetracarboxylic Acid

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Abstract

A new complex [Co(H2pztc)(bpy)H2O] (H4pztc = pyrazine-2,3,5,6-tetracarboxylic acid, bpy = 2,2′-bipyridine) has been synthesized by hydrothermal reactions of Co(NO3)2 · 6H2O with H4pztc and bpy and characterized by IR and X-ray diffraction single crystal structure analysis. It belongs to monoclinic system, P21/c space group with a = 13.454(2) Å, b = 12.939(2) Å, c = 11.4993(19) Å, α = 90°, β = 111.640(3)°, γ = 90°. This complex is assembled into 3D supramolecular architecture by hydrogen bonds (O–H···O, C–H···O).

Index Abstract

A new complex of cobalt(II) with pyrazine-2,3,5,6-tetracarboxylic acid and 2,2′-bipyridine is assembled by intermolecular hydrogen bonds forming 2D layer and 3D supramolecular network.

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References

  1. Wang FQ, Wang DF, Zhang XJ, Zhang JJ, Ma H, Jin LP (2007) Inorg Chim Acta 360:2029

    Google Scholar 

  2. Wang FO, Zhuang WJ, Jin LP (2007) J Mol Struct 832:48

    Article  CAS  Google Scholar 

  3. (a) Ghosh SK, Bharadwaj PK (2004) Inorg Chem 43:6887, (b) Ghosh SK, Bharadwaj PK (2005) Eur J Inorg Chem 4880, (c) Ghosh SK, Bharadwaj PK (2006) J Mol Struct 796:119, (d) Ghosh SK, Ribas J, Bharadwaj PK (2006) Inorg Chim Acta 359:468

  4. Wolff L (1987) Chem Ber 20:425

    Google Scholar 

  5. Sheldrick GM (1997) SADABS. Program for Empirical Absorption Correction of the Area Detector Data. University of Göttingen, Germany

    Google Scholar 

  6. Sheldrick GM (1997) SHELXS-97. Program for Crystal Structure Solution. University of Göttingen, Germany

    Google Scholar 

  7. Sheldrick GM (1997) SHELXL-97. Program for X-ray Crystal Structure Refinement. University of Göttingen, Germany

    Google Scholar 

  8. Desiraju GR, Steiner T (2001) In: Structural chemistry and biology. Oxford IUCr

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Tianjin University, Tianjin, 300072, P.R. China

    Su-Rong Fang, Ai-Hong Yang, Yan-Ping Zhang, Hong-Ling Gao & Jian-Zhong Cui

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  1. Su-Rong Fang
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  2. Ai-Hong Yang
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  3. Yan-Ping Zhang
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  4. Hong-Ling Gao
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  5. Jian-Zhong Cui
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Correspondence to Jian-Zhong Cui.

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Fang, SR., Yang, AH., Zhang, YP. et al. Synthesis, Crystal Structure of a New Co(II) Complex with Pyrazine-2,3,5,6-tetracarboxylic Acid. J Chem Crystallogr 38, 393–396 (2008). https://doi.org/10.1007/s10870-008-9328-8

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  • DOI: https://doi.org/10.1007/s10870-008-9328-8

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