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Synthesis, Structure and Properties of (H2NCH2CH2NH3)3 {(VO)6 [B10O16 (OH)6]2} · 11H2O

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Abstract

A new polyoxovanadoborate cluster (H2NCH2CH2NH3)3 {(VO)6[B10O16(OH)6]2} · 11H2O was prepared by hydrothermal technique and characterized by single crystal X-ray diffraction analysis, IR and TGA. The crystal of the new compound belongs to monoclinic system, space group C2/c with a = 20.198(1) Å, b = 13.4476(8) Å, c = 21.602(1) Å, β = 97.067(1)°, V = 5822.8(5) Å3, Z = 4, D c  = 1.956 g cm−3, M = 1714.4, μ = 1.066 mm−1, S = 1.905, R = 0.059, R w  = 0.0966.

Index Abstract

A new polyoxovanadoborate cluster (H2NCH2CH2NH3)3{(VO)6 [B10O16(OH)6]2} · 11H2O was prepared by hydrothermal technique and characterized by single crystal X-ray diffraction analysis, IR and TGA.

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Acknowledgement

The authors express their gratitude for the support of this work by the Natural Science Foundation of China (No. 20273021)

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Authors and Affiliations

  1. Department of Chemistry, East China Normal University, 3663 Zhongshan Road North, Shanghai, 200062, People’s Republic of China

    Qinghai Cai & Yongkui Shan

  2. Department of Chemistry, Harbin Normal University, 3663 Zhongshan Road North, Shanghai, 200062, People’s Republic of China

    Qinghai Cai, Bin Lu & Jiawei Zhang

Authors
  1. Qinghai Cai
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  2. Bin Lu
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  3. Jiawei Zhang
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  4. Yongkui Shan
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Correspondence to Yongkui Shan.

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Cai, Q., Lu, B., Zhang, J. et al. Synthesis, Structure and Properties of (H2NCH2CH2NH3)3 {(VO)6 [B10O16 (OH)6]2} · 11H2O. J Chem Crystallogr 38, 321–325 (2008). https://doi.org/10.1007/s10870-008-9325-y

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  • DOI: https://doi.org/10.1007/s10870-008-9325-y

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