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Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer

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Abstract

A novel three-dimensional coordination polymer [Ni(pca)2(H2O)]n (1) (pca = 2-pyrazinecarboxylate) has been synthesized by refluxing NiCl2·(H2O)6 with pcaH (pcaH = 2-pyrazinecarboxcylic acid). Complex 1 contains one-dimensional zigzag chains that are H-bonded to adjacent chains, generating a three-dimensional network that crystallizes in the P212121 space group, and is isostructural with a previous structure containing Co (Liang et al. Inorg Chim Acta 328:152–158, 2002). In structure 1, a = 7.79(6), b = 9.90(8), and c = 14.90(12) Å.

Graphical Abstract

Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer

Kathryn L. Seward, Joseph M. Ellsworth, Mark D. Smith, Hans-Conrad zur Loye

A novel three-dimensional coordination polymer [Ni(pca)2(H2O)]n (1) (pca = 2-pyrazinecarboxylate) has been synthesized by refluxing NiCl2·(H2O)6 with pcaH (pcaH = 2-pyrazinecarboxcylic acid) and characterized by single crystal X-ray diffraction

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Acknowledgements

Financial support from the National Science Foundation through Grant CHE-0714439 and the University of South Carolina Nano center is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208, USA

    Kathryn L. Seward, Joseph M. Ellsworth, Mark D. Smith & Hans-Conrad zur Loye

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  1. Kathryn L. Seward
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  2. Joseph M. Ellsworth
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  3. Mark D. Smith
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  4. Hans-Conrad zur Loye
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Correspondence to Hans-Conrad zur Loye.

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Seward, K.L., Ellsworth, J.M., Smith, M.D. et al. Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer. J Chem Crystallogr 38, 239–242 (2008). https://doi.org/10.1007/s10870-008-9321-2

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  • DOI: https://doi.org/10.1007/s10870-008-9321-2

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