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Diaquabis(phen)Ni(II) Complex with Vitamin B13 Counter-ions

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Abstract

The synthesis and crystal structure of a new Ni(II) complex of stoichiometry [Ni(phen)2(H2O)2](H2Or)2 · 2H2O, where phen is phenanthroline and H2Or is oratate monoanion, are reported. The complex [Ni(phen)2(H2O)2](H2Or)2 · 2H2O crystallizes in the monoclinic system with space group C2/c and cell parameters a = 16.1661(8) Å, b = 12.5669(7) Å and c = 16.4752(7) Å. The coordination around Ni(II) is a distorted octahedron with two phen ligands perpendicular to each other and two aqua ligands in cis- position. Orotate ions locate themselves out of the coordination sphere and bridge the [Ni(phen)2(H2O)2]2+ moieties through hydogen bonding with aqua ligands. The FT-IR spectrum of the complex and thermal decomposition behaviour are also briefly discussed.

Graphical Abstract

Diaquabis(phen)Ni(II) Complex with Vitamin B13 Counter-ions

Dursun Ali Köse, Birgül Zümreoglu-Karan, Başak Koşar, Orhan Büyükgüngör

A new complex where Vitamin B13 monoanions act as counter ions and bridge the [Ni(phen)2(H2O)2]2+ units by hydrogen bonds is described

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Acknowledgements

This work was supported by the Turkish Scientific and Technical Research Council through the project TBAG 2236. The authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased under grant No. F279 of the University Research Fund).

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Authors and Affiliations

  1. Department of Chemistry, Hacettepe University, Beytepe Campus, 06800, Ankara, Turkey

    Dursun Ali Köse & Birgül Zümreoglu-Karan

  2. Hacettepe Universitesi Fen Fakultesi, Kimya Bolumu, Beytepe Kampusu, 06532, Ankara, Turkey

    Dursun Ali Köse

  3. Department of Physics, Faculty of Art and Science, Ondokuzmayıs University, Samsun, Turkey

    Başak Koşar & Orhan Büyükgüngör

Authors
  1. Dursun Ali Köse
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  2. Birgül Zümreoglu-Karan
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  3. Başak Koşar
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  4. Orhan Büyükgüngör
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Correspondence to Dursun Ali Köse.

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CCDC deposition number is 606339.

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Köse, D.A., Zümreoglu-Karan, B., Koşar, B. et al. Diaquabis(phen)Ni(II) Complex with Vitamin B13 Counter-ions. J Chem Crystallogr 38, 305–309 (2008). https://doi.org/10.1007/s10870-007-9309-3

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  • DOI: https://doi.org/10.1007/s10870-007-9309-3

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