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Synthesis and Structure of the Dimeric Copper(II) Complex Tetrakis[N-thiazol-2-yl-(4-methylphenyl)sulfonamidate]dicopper(II)

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Abstract

The coordination chemistry of the ligand N-thiazol-2-yl-toluenesulfonamidate towards the copper(II) ion has been investigated using an electrochemical synthesis method. The X-ray structure of this complex was elucidated and is discussed. The compound crystallised in the monoclinic crystal system, P21/c space group with a = 17.3888(9), b = 16.3003(9), c = 18.3679(9) Å and β = 114.3640(10)°. Four bidentate sulfathiazolato anions bridge two metal centers in a paddle-wheel fashion, with the nitrogen atoms as donors to give a dimeric species with a Cu···Cu distance of 2.7859(5) Å.

Graphical Abstract

The coordination chemistry of the ligand N-thiazol-2-yl-toluenesulfonamidate towards the copper(II) ion has been investigated using an electrochemical synthesis method. The X-ray structure of the product has been elucidated and is discussed. Sulfathiazolato anions act as bridging ligands to give a dimeric species with a Cu···Cu distance of 2.7859(5) Å.

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Authors and Affiliations

  1. Departamento de Química Inorgánica, Universidade de Vigo, 36310, Vigo, Galicia, Spain

    Santiago Cabaleiro, Jesús Castro & Paulo Pérez-Lourido

  2. Departamento de Física e Informática, Universidade de São Paulo, CP 369, Sao Carlos, 13560-970, Brazil

    Rafael Calvo, Lia M. B. Napolitano & Otaciro R. Nascimento

  3. Departamento de Química Inorgánica, Universidade de Santiago de Compostela, Santiago, 15782, Galicia, Spain

    J. Arturo García-Vázquez, Jaime Romero & Antonio Sousa

  4. Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral, INTEC (CONICETUNL), 3000, Santa Fe, Argentina

    Rafael Calvo

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  1. Santiago Cabaleiro
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  2. Rafael Calvo
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  4. J. Arturo García-Vázquez
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Correspondence to Jesús Castro.

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Cabaleiro, S., Calvo, R., Castro, J. et al. Synthesis and Structure of the Dimeric Copper(II) Complex Tetrakis[N-thiazol-2-yl-(4-methylphenyl)sulfonamidate]dicopper(II). J Chem Crystallogr 38, 71–75 (2008). https://doi.org/10.1007/s10870-007-9303-9

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