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Synthesis and Structure of a New Coordination Polymer [Cd(pzdc)(bpy)]n (H2pzdc = Pyrazine-2,3-dicarboxylic Acid, bpy = 2,2′-Bipyridine)

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Abstract

A new 3D coordination polymer, [Cd(pzdc)(bpy)]n (1) (pzdc = pyrazine-2,3-dicarboxylic acid, bpy = 2,2′-bipyridine), has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 (C16H10CdN4O4) crystallizes in monoclinic space group P21/c, features an interesting 3D zipper-like networks constructed by 2D layers via strong π–π packing interactions. Cell unit parameter for 1: a = 9.767(1), b = 14.022(2), c = 13.719(2) Å, β = 100.86(1)o, and Z = 4.

Graphical Abstract

A new 3D coordination polymer, [Cd(pzdc)(bpy)]n (pzdc = pyrazine-2,3-dicarboxylic acid, bpy = 2,2′-bipyridine), has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction. X-ray diffraction analysis reveals that [Cd(pzdc)(bpy)]n features an interesting 3D zipper-like networks constructed by 2D layers via strong π–π packing interactions.

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References

  1. (a) Mathate P, Madras G, Natarajan S (2006) J Phys Chem B 110:13759; (b) Ocwig NW, Friedrichs OD, O’Keeffe M, Yaghi OM (2005) Acc Chem Res 38:176; (c) Bradshaw D, Claridge JB, Cussen EJ, Prior TJ, Rosseinksy MJ (2005) Acc Chem Res 38:273; (d) Rao CNR, Natarajan S, Vaidhyanathan R (2004) Angew Chem Int Ed 43:1466

  2. (a) Moulton B, Zawarotko MJ (2001) Chem Rev 101:1629; (b) Seo JS, Whang D, Lee H, Jun SI, Oh J, Jeon YJ, Kim K (2000) Nature 404:982; (c) Tao J, Tong ML, Shi JX, Chen XM, Ng SW (2000) Chem Commun 2043

  3. Shin DM, Lee IS, Lee YA, Chung YK (2003) Inorg Chem 42:2977

    Article  CAS  Google Scholar 

  4. Withersby MA, Blake AJ, Champness NR, Cooke PA, Hubberstey P, Li WS, Schroder M (1999) Inorg Chem 38:2259

    Article  CAS  Google Scholar 

  5. Shin DM, Lee IS, Chung YK, Lah MS (2003) Inorg Chem 42:5459

    Article  CAS  Google Scholar 

  6. (a) Ma BQ, Sun HL, Gao S (2005) Inorg Chem 44:837; (b) Yang J, Ma JF, Liu YY, Li SL, Zheng GL (2005) Eur J Inorg Chem 2174

  7. (a) Tong ML, Hu S, Wang J, Kitagawa S, Ng SW (2005) Cryst Growth Des 5:837; (b) Zhao B, Yi L, Dai Y, Chen XY, Cheng P, Liao DZ, Yan SP, Jiang ZH (2005) Inorg Chem 44:911

  8. Pan L, Frydel T, Sander M, Huang XY, Li J (2001) Inorg Chem 40:1271

    Article  CAS  Google Scholar 

  9. Lu WG, Jiang L, Feng XL, Lu TB (2006) Cryst Growth Des 6:564

    Article  CAS  Google Scholar 

  10. (a) O’Connor CJ, Klein CL, Majeste RJ, Trefonas LM (1982) Inorg Chem 21:64; (b) O’Connor CJ, Sinn E (1981) Inorg Chem 20:545

  11. (a) Kubota Y, Takata M, Matsuda R, Kitaura R, Kitagawa S, Kato K, Sakuta M, Kobayashi TC (2005) Angew Chem Int Ed 44:920; (b) Gryz M, Starosta W, Leciejewicz J (2005) J Coord Chem 58:931

    Google Scholar 

  12. (a) Sheldrick GM (1997) SHELXTL97, Program for Crystal Structure Refinement, University of Göttingen, Germany; (b) Sheldrick GM (1997) SHELXS97, Program for Crystal Structure Solution, University of Göttingen, Germany; (c) Sheldrick GM (1990) Acta Crystallogr Sect A 46:467

  13. Wang XL, Qin C, Wang EB, Li YG, Hao N, Hu CW, Xu L (2004) Inorg Chem 43:1850

    Article  CAS  Google Scholar 

  14. (a) Zheng SL, Tong ML, Fu RW, Chen XM, Ng SW (2001) Inorg Chem 40:3562; (b) Zhang XM, Tong ML, Feng SH, Chen XM (2001) J Chem Soc Dalton Trans 2069; (c) Chen XM, Liu GF (2002) Chem Eur J 8:4811

  15. Shi Q, Cao R, Sun DF, Hong MC, Liang YC (2001) Polyhedron 20:3287

    Article  CAS  Google Scholar 

  16. Han ZB, Cheng XN, Chen XM (2005) Cryst Growth Des 5:695

    Article  CAS  Google Scholar 

  17. Han ZB, Ma Y, Sun ZG, You WS (2006) Inorg Chem Commun 9:844

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was granted financial support from the Program for Liaoning Excellent Talents in University(RC-05-11).

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  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    Yi Ma, Yong-Ke He, Li-Tian Zhang, Jing-Qun Gao & Zheng-Bo Han

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  1. Yi Ma
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  2. Yong-Ke He
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Correspondence to Zheng-Bo Han.

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Ma, Y., He, YK., Zhang, LT. et al. Synthesis and Structure of a New Coordination Polymer [Cd(pzdc)(bpy)]n (H2pzdc = Pyrazine-2,3-dicarboxylic Acid, bpy = 2,2′-Bipyridine). J Chem Crystallogr 38, 267–271 (2008). https://doi.org/10.1007/s10870-007-9293-7

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