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Synthesis and Crystal Structure of One-Dimensional Carboxylate-Bridged Copper(II) Complex with 2-Pyridylmethylamino-3-butyric acid

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Abstract

The tridentate Schiff base carboxylate-containing ligand 2-pyridylmethylamino-3-butyric acid (Hpaba) reacts with copper(II) perchlorate to give the one-dimensional chain complex {[Cu(μ-paba)](ClO4)·H2O} n (1). The coordination geometry of each copper(II) ion is best described as a square-plane with two nitrogen atoms and one carboxylate oxygen atom of the ligand, and one carboxylate oxygen atom belong to another ligand. It crystallizes in the monoclinic system P21/c with a = 12.717(2), b = 7.9163(15), c = 14.981(2) Å, β = 111.14(1)°, V = 1406.8(4) Å3, Z = 4. Cyclic voltammogram of 1 undergoes the reversible one-electron oxidation to the Cu(III) and the reversible one-electron reduction to the Cu(I) state.

Graphical Abstract

Crystal structure of 1 reveals a syn-anti carboxylate-bridged one dimensional chain complex in which the coordination environment around each copper(II) ion exhibits a distorted square plane.

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Acknowledgement

This study was financially supported by Kongju National University in the 2007 Star Project Program.

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  1. Department of Chemistry Education, Kongju National University, Kongju, 314-701, Korea

    Ki-Young Choi

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  1. Ki-Young Choi
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Correspondence to Ki-Young Choi.

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Choi, KY. Synthesis and Crystal Structure of One-Dimensional Carboxylate-Bridged Copper(II) Complex with 2-Pyridylmethylamino-3-butyric acid. J Chem Crystallogr 38, 53–56 (2008). https://doi.org/10.1007/s10870-007-9280-z

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  • DOI: https://doi.org/10.1007/s10870-007-9280-z

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