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Crystal Study of Salicylaldehyde N(4)-Phenylthiosemicarbazone

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Abstract

The crystal structure of salicylaldehyde N(4)-phenyl thiosemicarbazone is described. The compound crystallizes in the triclinic crystal system, space group P \( \bar 1, \) Z = 6, V = 2002.1(5) Å3 with unit cell parameters a = 10.6733(15) Å, b = 13.8856(19) Å, c = 14.052(2) Å, α = 81.851(2)°, β = 77.061(2)° and γ = 83.482(2)°. There are three independent molecules in the asymmetric unit. The crystal structure reveals that the compound exists in the thione form and S1 and N3 are at E configuration to each other with respect to N2–C7 bond. Similarly, S2 and N6 are trans to each other with respect to N5–C21 bond in the second molecule of the asymmetric unit and S3 and N9 are trans to each other with respect to N8–C35 bond in the third molecule of the asymmetric unit. The packing of the molecules in the crystal lattice is stabilized by intermolecular hydrogen bonds.

Index Abstract

The compound salicylaldehyde N(4)-phenyl thiosemicarbazone crystallizes in the triclinic crystal system, space group P \( \bar 1, \) Z = 6, V=2002.1(5) Å3 with unit cell parameters a = 10.6733(15) Å, b = 13.8856(19) Å, c = 14.052(2) Å, α = 81.851(2)°, β = 77.061(2)° and γ = 83.482(2)°.

The structure of the compound salicylaldehyde N(4)-phenylthiosemicarbazone

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Acknowledgments

The authors are thankful to the CSIR, New Delhi, India for financial assistance.

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Authors and Affiliations

  1. Department of Applied Chemistry, Cochin University of Science and Technology, Kochi , 682 022, Kerala, India

    E. B. Seena & M. R. Prathapachandra Kurup

  2. Analytical Science Division, Central Salt and Marine Chemicals Research Institute, Bhavnagar , 364 002, Gujarat, India

    E. Suresh

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  1. E. B. Seena
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  2. M. R. Prathapachandra Kurup
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  3. E. Suresh
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Correspondence to M. R. Prathapachandra Kurup.

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Seena, E.B., Prathapachandra Kurup, M.R. & Suresh, E. Crystal Study of Salicylaldehyde N(4)-Phenylthiosemicarbazone. J Chem Crystallogr 38, 93–96 (2008). https://doi.org/10.1007/s10870-007-9268-8

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  • DOI: https://doi.org/10.1007/s10870-007-9268-8

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