Abstract
The crystal structure of a metallohybrid carboxylic acid obtained from the reaction of 1,3,5-benzenetricarboxylic acid (TCAH3) with copper(II)acetate monohydrate in the presence of pyridine (py) having composition Cu(py)2(TCAH2)2(H2O)2 [1] is reported. It crystallizes in triclinic space group P-1 and with a = 7.0110(3)Å, b = 8.9523(5)Å, c = 11.5370(5) Å, α = 79.776(3) °, β = 82.881(3)°, γ = 83.628(3)°, and V = 704.18(6)Å3. The hydrogen bond in 1 is compared with the hydrogen bond pattern in the structure of 1,3-dicarbomethoxy 4,6-benzenedicarboxylic acid, which crystallizes in mononclinic space group P21/c and has unit cell parameters of a = 6.9549(16)Å, b = 8.7676(15)Å, c = 20.111(4)Å; β = 92.585(17) ° and V = 1225.1(4) Å3.
Index Abstract
Crystal structure of a metallohybrid carboxylic acid obtained from the reaction of 1,3,5-benzenetricarboxylic acid with copper(II)acetate monohydrate in the presence of pyridine is determined and compared with hydrogen bond pattern present in the structure of 1,3-dicarbomethoxy 4,6-benzenedicarboxylic acid.
Crystal structure of a metallohybrid acid of 1,3,5-benzenetricarboxylic acid of copper(II).
Kusum Bania, Nilotpal Barooah, Rupam Sarma, Jubaraj B. Baruah
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The authors thank the Department of Science and Technology, New-Delhi for financial support.
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Bania, K., Barooah, N., Sarma, R. et al. Crystal Structure of a Metallohybrid Acid of 1,3,5-Benzenetricarboxylic Acid of Copper(II). J Chem Crystallogr 38, 57–60 (2008). https://doi.org/10.1007/s10870-007-9262-1
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DOI: https://doi.org/10.1007/s10870-007-9262-1