Abstract
This paper describes the solid-state synthesis and systematic studies of versatile supramolecular self-assembly of 14 new series of organic salt cocrystals. Hierarchical self-assembly in the solid state utilizes the cooperative interaction of hydrogen bonding, electrostatic and π–π interactions. These salts are crystallized as a highly ordered self-assembly directed by intermolecular non-covalent interaction.
Index Abstract
Fourteen cocrystals of organic salt have been characterized by single crystal X-ray diffraction and their solid-state packing pattern has been compared.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Lehn JM (2002) Science 295:2400
Dugas H (1996) Bioorganic chemistry, 3rd edn. Springer, Berlin
Colfen H, Mann S (2003) Angew Chem Int Ed 42:2350
Cann AJ (2001) Principles of molecular virology. Academic Press, San Diego
Fyfe MCT, Stoddart JF (1997) Acc Chem Res 30:393
Seidel SR, Stang PJ (2002) Acc Chem Res 35:972
Desiraju GR (1989) Crystal engineering. The design of organic solids. Elsevier Science Publishers BV, Amsterdam
Desiraju GR, Steiner T (2001) The weak hydrogen bond in structural chemistry and biology. Oxford University Press, Oxford
Steiner T (2002) Angew Chem Int Ed 41:49
Pollino JM, Weck M (2005) Chem Soc Rev 34:193
Desiraju GR (ed) (1996) Perspectives in supramolecular chemistry: the crystal as a supramolecular entity, vol 2. Wiley, Chichester
Muller-Dethlefs K, Hobza P (2000) Chem Rev 100:143
Braga D, Brammer L, Champness NR (2005) CrystEngComm 7:1
Lehn JM (1995) Supramolecular chemistry: concepts and perspectives. VCH, Meinheim
Steed JW, Atwood JL (2001) Supramolecular chemistry. Wiley, New York
Sauvage JP (1999) Transition metals in suparamolecular chemistry. Wiley, New York
Bowden NB, Weck M, Choi IS, Whitesides GM (2001) Acc Chem Res 34:231
Sijbesma RP, Meijer EW (2003) Chem Commun 5
Pease AR, Jeppesen JOJ, Stoddart F, Luo Y, Collier CP, Heath JR (2001) Acc Chem Res 34:433
Ajayaghosh A, George SJJ (2001) Am Chem Soc 123:5148
Stahl PH, Wermuth CG (2002) Handbook of pharmaceutical salts: properties, selection and use. Verlag Helvetica Chimica Acta, Zurich
Vazquez-Tato MP (1993) Synlett 1993:506
Juric BS, Zdravkovski Z (1993) Symn Comm 23:2761
McPolloch J, Ubelohde AR (1956) Trans Faraday Soc 52:1112
Rivera JM, Martin T, Rebek J Jr (1989) J Am Chem Soc 120:819
Russell VA, Evans CC, Li W, Ward MD (1997) Science 276:575
Toda F (1993) Synlett 1993:303
SMART, SAINT and XPREP (1995) Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA
Sheldrick GM (1999–2003) SADABS: empirical software for absorption and correction. University of Gottingen, Institut fur Anorganische Chemieder Universitat, Tammanstrasse 4, D-3400 Gottingen, Germany
Sheldrick GM (1997) SHELXS-97. University of Gottingen, Germany
Burnett MN, Johnson CK (1996) ORTEP-III: Oak Ridge thermal ellipsoid plot program for crystal structure illustrations. Oak Ridge National Laboratory Report ORNL-6895
Acknowledgements
The financial support from the Council of Scientific and Industrial Research (CSIR) of India to GD and HT (Grant no. 01(1948)/04/EMR-II) is gratefully acknowledged. BMB and AP are thankful to CSIR for JRF. We thank Central Instrument Facility and Department of Chemistry IIT Guwahati for Single crystal XRD measurements.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Thakuria, H., Borah, B.M., Pramanik, A. et al. Solid State Synthesis and Hierarchical Supramolecular Self-assembly of Organic Salt Cocrystals. J Chem Crystallogr 37, 807–816 (2007). https://doi.org/10.1007/s10870-007-9252-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10870-007-9252-3