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Synthesis, Structural Characterization and Spectroscopic Properties of [Pt(bddn)]Cl2 · 3.5H2O (bddn = 1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonane)

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Abstract

The reaction of the potentially tetradentate ligand 1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonane (bddn) with [PtCl2(CH3CN)2] yields a mixture of complexes, where the ligand acts as bidentate SS, or tetradentate 2NS or NSSN. This mixture of complexes SS, 2NS, and NSSN was crystallized with dichloromethane/n-pentane (1:1) and crystals of [Pt(bddn)]Cl2 (isomer NSSN) were obtained. The complex has been characterized by elemental analyses, mass spectrometry, conductivity, IR, 1H, 13C{1H}, 1H{195Pt}, 195Pt{1H}NMR, HSQC and NOESY spectroscopies, and X-ray diffraction. Compound [PtCl2(bddn)] · 3.5H2O crystallizes in the monoclinic space group C2/c with unit cell dimensions a = 15.430(7) Å, b = 17.405(4) Å, c = 18.887(7) Å, β = 91.24(2)°, V = 5071(3) Å3, Z = 4, R 1 = 0.0354, wR2 = 0.1034. This compound consist of discrete cations [Pt(bddn)]2+, Cl− anions and water molecules of crystallization. The platinum(II) is tetracoordinated by two azine nitrogen atoms and two sulfur atoms of the thioether-pyrazole ligand, in a distorted square planar geometry.

Graphical Abstract

Synthesis, Structural Characterization and Spectroscopic Properties of [Pt(bddn)]Cl 2  · 3.5H 2 O (bddn = 1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonane)

Antonio de Leon, Josefina Pons*, Jordi García-Antón, Xavier Solans, Mercè Font-Bardia, Josep Ros*

Reaction of the ligand 1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonane (bddn) with [PtCl2(CH3CN)2], yields a mixture of complexes. The mixture was crystallized with dichloromethane/pentane (1:1) and crystals of [Pt(bddn)]Cl2 · 3.5 H2O was obtained.

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References

  1. Kresze G (1984) Stud Inorg Chem 5:93

    CAS  Google Scholar 

  2. Senning A (1971, 1982) In: Sulphur in organic and inorganic chemistry, vols. I and IV. Elsevier Science Publishers, Amsterdam

  3. Murray SG, Hartley FR (1981) Chem Rev 81:365 and references cited therein

    Article  CAS  Google Scholar 

  4. Haanstra WG, Driessen WL, Reedijk J, Turpeinen U, Hämäläinen R (1989) J Chem Soc Dalton Trans 2309

  5. Haanstra WG, van der Donk WAJW, Driessen WL, Reedijk J, Drew MGB (1990) J Chem Soc Dalton Trans 3123

  6. Haanstra WG, van der Donk WAJW, Driessen WL, Reedijk J, Drew MGB, Wood JS (1990) Inorg Chim Acta 176:299

    Article  CAS  Google Scholar 

  7. Haanstra WG, Driessen WL, Reedijk J, Fröhlich R, Krebs B (1991) Inorg Chim Acta 185:175

    Article  CAS  Google Scholar 

  8. Haanstra WG, Driessen WL, de Graaff RAG, Reedijk J, Wang YF, Stam CH (1991) Inorg Chim Acta 186:215

    Article  CAS  Google Scholar 

  9. Sorrell TN, Malachowski MR (1983) Inorg Chem 22:1883

    Article  CAS  Google Scholar 

  10. Mukherjee R (2000) Coord Chem Rev 203:151

    Article  CAS  Google Scholar 

  11. Ajellal N, Kuhn MCA, Boff ADG, Hörner M, Thomas CM, Carpentier JF, Casagrande OL Jr (2006) Organometallics 25:1213

    Article  CAS  Google Scholar 

  12. Alves S, Paulo A, Correia JDG, Cano L, Smith CJ, Hoffman TJ, Santos I (2005) Bioconjugate Chem 16:438

    Article  CAS  Google Scholar 

  13. Ghosh P, Wood M, Bonanno JB, Hascall T, Parkin G (1999) Polyhedron 18:1107

    Article  CAS  Google Scholar 

  14. García-Antón J, Pons J, Solans X, Font-Bardía M, Ros J (2003) Eur J Inorg Chem 3952

  15. de León A, Pons J, García-Antón J, Solans X, Font-Bardía M, Ros J (2007) Polyhedron 26:2498

    Article  Google Scholar 

  16. García-Antón J, Pons J, Solans X, Font-Bardía M, Ros J (2002) Eur J Inorg Chem 3319

  17. Rimola A, Sodupe M, Ros J, Pons J (2006) Eur J Inorg Chem 447

  18. de León A, Pons J, García-Antón J, Solans X, Font-Bardía M, Ros J (2007) Inorg Chim Acta 360:2071

    Article  Google Scholar 

  19. García-Antón J, Mathieu R, Lugan N, Pons J, Ros J (2004) J Organomet Chem 1599

  20. de León A, Pons J, García-Antón J, Solans X, Font-Bardía M, Ros J (2007) Polyhedron 26:2921

    Article  Google Scholar 

  21. García-Antón J, Pons J, Solans X, Font-Bardía M, Ros J (2004) Acta Cryst E60:m1087

    Google Scholar 

  22. Fanizzi FP, Intini FP, Maresca L, Natile G (1990) J Chem Soc Dalton Trans 199

  23. Sheldrick GM (1997) SHELXS97, Program for crystal structure determination. University of Göttingen, Germany

    Google Scholar 

  24. Sheldrick GM (1997) SHELXL97, Program for crystal structure refinement. University of Göttingen, Germany

    Google Scholar 

  25. Geary WJ (1971) Coord Chem Rev 7:81

    Article  CAS  Google Scholar 

  26. Williams DH, Fleming I (1995) Spectroscopic methods in organic chemistry. McGraw-Hill, London

    Google Scholar 

  27. Nakamoto K (1986) Infrared and Raman spectra of inorganic coordination compounds. John Wiley and Sons, New York

    Google Scholar 

  28. Grant GJ, Patel KN, Helm ML, Mehne LF, Klinger DW, VanDerveer DG (2004) Polyhedron 23:1361

    Article  CAS  Google Scholar 

  29. Mitchell KA, Jensen CM (1995) Inorg Chem 34:4441

    Article  CAS  Google Scholar 

  30. Allen FA (2002) Acta Crystallogr B58:380

    CAS  Google Scholar 

Download references

Acknowledgement

Support by the Spanish Ministerio de Educación y Cultura (project CTQ2007-63913 BQU) is gratefully acknowledged.

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Authors and Affiliations

  1. Departament de Química, Facultat de Ciències, Unitat de Química Inorgànica, Universitat Autònoma de Barcelona, Bellaterra, Barcelona, 08193, Spain

    Antonio de Leon, Josefina Pons, Jordi García-Antón & Josep Ros

  2. Cristal.lografia, Mineralogia i Dipòsits Minerals, Universitat de Barcelona, Martí i Franquès s/n, Barcelona, 08028, Spain

    Xavier Solans & Mercè Font-Bardia

Authors
  1. Antonio de Leon
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  2. Josefina Pons
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  3. Jordi García-Antón
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  4. Xavier Solans
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  5. Mercè Font-Bardia
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  6. Josep Ros
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Correspondence to Josefina Pons.

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de Leon, A., Pons, J., García-Antón, J. et al. Synthesis, Structural Characterization and Spectroscopic Properties of [Pt(bddn)]Cl2 · 3.5H2O (bddn = 1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonane). J Chem Crystallogr 37, 801–805 (2007). https://doi.org/10.1007/s10870-007-9251-4

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  • DOI: https://doi.org/10.1007/s10870-007-9251-4

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