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One Novel Three-dimensional Network Constructed from [Mn(4,4′-bip)2(OH2)4]2+ Cations and DBA2− Anions via Hydrogen-bonding and π–π Interactions

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Abstract

One new mononuclear manganese complex of [Mn(4,4′-bip)2(OH2)4](DBA) · 4H2O (1) (4,4′-bipyridine, 4,4′-bip; H2DBA, benzene-1,3-dicarboxylic acid) has been obtained from the hydrothermal reaction of MnCl2 · 4H2O, 4,4′-bipyridine and H2DBA in the solvent of H2O at 140 °C for 3 days, characterized by X-ray analysis, spectroscopic methods, and thermal analysis. Packing diagram shows that the three-dimensional network was formed via hydrogen bonds and strong π–π interactions.

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One Novel Three-dimensional Network Constructed from [Mn(4,4′-bip) 2 (OH 2 ) 4 ] 2+ Cations and DBA 2− Anions via Hydrogen-bonding and π–π Interactions

Ying Liu, Bao Zhang, Jian-min Dou, Da-qi Wang, Da-cheng Li, Lei Zhou

One new mononuclear manganese complex of [Mn(4,4’-bip)2(OH2)4](DBA) · 4H2O (1) (4,4’-bipyridine, 4,4’-bip; H2DBA, benzene-1, 3-dicarboxylic acid) has been obtained and haracterized by X-ray analysis, spectroscopic methods, and thermal analysis. Packing diagram shows that the three-dimensional network was formed via hydrogen bonds and strong π-π interactions.

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Acknowledgments

The work was supported by Liaocheng University (31801), Liaocheng, P. R. China.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, P.R. China

    Ying Liu, Bao Zhang, Jian-Min Dou, Da-Qi Wang, Da-Cheng Li & Lei Zhou

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  1. Ying Liu
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  2. Bao Zhang
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  3. Jian-Min Dou
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  4. Da-Qi Wang
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  5. Da-Cheng Li
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  6. Lei Zhou
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Correspondence to Ying Liu.

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Liu, Y., Zhang, B., Dou, JM. et al. One Novel Three-dimensional Network Constructed from [Mn(4,4′-bip)2(OH2)4]2+ Cations and DBA2− Anions via Hydrogen-bonding and π–π Interactions. J Chem Crystallogr 37, 717–720 (2007). https://doi.org/10.1007/s10870-007-9222-9

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  • DOI: https://doi.org/10.1007/s10870-007-9222-9

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