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Synthesis, Spectroscopic and Crystal Structure Analysis of N-[imidazolidin-2-ylidene]-5-(thien-2-yl)[1,3,4]thiadiazole-2-amine

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Abstract

The crystal structure of the title compound has been determined. The compound crystallizes in the monoclinic space group P21/c with a = 5.9885(2) Å, b = 14.7345(4) Å, c = 12.3719(4) Å, β = 96.655(5)°, V = 1084.31(8) Å3, z = 4. An intramolecular N–H···N hydrogen bond forms a pseudo-six-membered ring with graph set S 1 1(6). The crystal structure is stabilized by intermolecular interactions of the type N–H···N and C–H···N. The packing motifs in accordance with Etter’s analysis are R 2 2(8) corresponding to N–H···N dimer and that generated by the chain is C(7).

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References

  1. Desai K, Baxi AJ (1992) Indian J Pharm Sci 54:183

    CAS  Google Scholar 

  2. Gawande NG, Shingare MS (1987) Indian J Chem 26B:387

    CAS  Google Scholar 

  3. Mamolo MG, Vio L, Banfi E (1996) Farmaco 51:71

    CAS  Google Scholar 

  4. Shucla MD, Desai NC, Astik RR, Thaker KA (1984) J Ind Chem Soc 61:168

    Google Scholar 

  5. Mullican MD, Wilson MW, Connor DT, Kostlan CR, Schrier DJ, Dyer RD (1993) J Med Chem 36:1090

    Article  CAS  Google Scholar 

  6. Chapleo CB, Myers M, Myers PL, Saville JF, Smith ACB, Stillings MR, Terlloch IF, Walter DS, Welbourn AP (1986) J Med Chem 29:2273

    Article  CAS  Google Scholar 

  7. Chapleo CB, Myers PL, Smith AC, Stillings MR, Tulloch IF, Walter DS (1988) J Med Chem 31:7

    Article  CAS  Google Scholar 

  8. Turner S, Myers M, Gadie B, Nelson AJ, Pape R, Saville JF, Doxey JC, Berridge TL (1988) J Med Chem 31:902

    Article  CAS  Google Scholar 

  9. Turner S, Myers M, Gadie B, Hale SA, Horsley A, Nelson AJ, Pape R, Saville JF, Doxey JC, Berridge TL (1988) J Med Chem 31:907

    Google Scholar 

  10. Mazzone G, Pignatello R, Mazzone S, Panico A, Penisi G, Castana R, Mazzone P (1993) Farmaco 48:1207

    CAS  Google Scholar 

  11. Miyamoto K, Koshiura R, Mori M, Yokoi H, Mori C, Husegawa T, Takatori K (1985) Chem Pharm Bull 33:5216

    Google Scholar 

  12. Kumar R, Giri S, Nizamuddin R (1988) J Ind Chem Soc 65:571

    CAS  Google Scholar 

  13. Mils J, Gleeson H, Seed A, Hint M, Stying P (1977) Mol Cryst LiqCryst 303:14

    Google Scholar 

  14. Bruker (1998) SAINTPLUS, Program for data reduction; Bruker Axs Inc, Madison, Wisconcin, USA

  15. Sheldrick GM (1997) SADABS, Program for absorption correction. University of Göttingen, Germany

    Google Scholar 

  16. Sheldrick GM (1997) SHELXS97, Program for the solution of crystal structures. University of Göttingen, Germany

    Google Scholar 

  17. Sheldrick GM (1997) SHELXL97, Program for crystal structure refinement. University of Göttingen, Germany

    Google Scholar 

  18. Nardelli M (1983) Acta Cryst C39:1141

    CAS  Google Scholar 

  19. Farrugia LJ (1997) J Appl Cryst 30:565

    Google Scholar 

  20. Spek AL (1997) PLUTON, Program for molecular graphics. University of Utrecht, The Netherlands

    Google Scholar 

  21. Watkin DM, Pearce L, Prout CK (1993) CAMERON, Program for molecular graphics. Chemical Crystallography Laboratory, University of Oxford, England

    Google Scholar 

  22. Ravikumar K, Shridhar B, Mahesh M, Narayan Reddy VV (2006) J Chem Cryst 36:381

    Article  CAS  Google Scholar 

  23. Begum NS, Vasundhara DE, Girija CR, Kolavi GD, Hegde VS, Khazi IM (2006) J Chem Res 5:286

    Article  Google Scholar 

  24. Begum NS, Vasundhara DE, Girija CR, Kolavi GD, Hegde VS, Khazi IM (2007) J Chem Cryst 37:193

    Article  CAS  Google Scholar 

  25. Begum NS, Vasundhara DE, Kolavi GD, Khazi IM (2007) Acta Cryst E63:o1955

    CAS  Google Scholar 

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Acknowledgements

NSB thanks UGC-DRS for financial support. DEV thanks UGC-FIP for the Teacher fellowship. The authors thank the Department of Science and Technology, India, for data collection on the CCD facility set up under the IRHPA-DST program.

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Authors and Affiliations

  1. Department of Studies in Chemistry, Bangalore University, Central College Campus, Bangalore, 560 001, India

    Noor Shahina Begum, D. E. Vasundhara & C. R. Girija

  2. Department of Chemistry, Karnatak University, Dharwad, 580 003, India

    G. D. Kolavi, V. S. Hegde & I. M. Khazi

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  1. Noor Shahina Begum
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  2. D. E. Vasundhara
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  3. C. R. Girija
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  4. G. D. Kolavi
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  5. V. S. Hegde
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  6. I. M. Khazi
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Correspondence to Noor Shahina Begum.

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Begum, N.S., Vasundhara, D.E., Girija, C.R. et al. Synthesis, Spectroscopic and Crystal Structure Analysis of N-[imidazolidin-2-ylidene]-5-(thien-2-yl)[1,3,4]thiadiazole-2-amine. J Chem Crystallogr 37, 561–565 (2007). https://doi.org/10.1007/s10870-007-9211-z

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