Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of Complex [Nd(2-FC6H4COO)3·(2-FC6H4COOH)·H2O]2

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The neodymium complex with 2-fluorobenzoic acid was synthesized and characterized by X-ray diffraction. The complex crystallizes in the triclinic system with space group Pī, lattice parameters: a = 9.2747(10) Å, b = 11.7594(13) Å, c = 13.5158(14) Å, α = 110.220(2)°, β = 93.930(2)°, γ = 90.894(2)°, V = 1378.8(3) Å3, Z = 1, Dcalc = 1.733 Mg/m3. The complex is a binuclear molecule in which four 2-fluorobenzoato groups act as bidentate and tridentate bridges between the two Nd3+ ions. Each Nd3+ ion is additionally chelated by one 2-fluorobenzoato group and coordinated by one 2-fluorobenzoic acid and one water molecule.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Reineke TM, Eddaoudi M, Fehr M, Kelley D, Yaghi OM (1999) J Am Chem Soc 121:1651

    Article  CAS  Google Scholar 

  2. Bettencourt-Dias A (2005) Inorg Chem 44:2734

    Article  CAS  Google Scholar 

  3. Chandler BD, Cramb DT, Shimizu GKH (2006) J Am Chem Soc 128:10403

    Article  CAS  Google Scholar 

  4. Viswanathan S, Bettencourt-Dias A de (2006) Inorg Chem 45:10138

    Article  CAS  Google Scholar 

  5. Yin MC, Ai CC, Yuan LJ, Wang CW, Sun JT (2004) J Mol Struct 691:33

    Article  CAS  Google Scholar 

  6. Yin MC, Yuan LJ, Ai CC, Wang CW, Yuan ET, Sun JT (2004) Polyhedron 23:529

    Article  CAS  Google Scholar 

  7. Duan ZB, Jin ZS, Hu NH, Ni JZ (1989) Chinese J Struct Chem 8:168

    CAS  Google Scholar 

  8. Ma JF, Jin ZS, Ni JZ (1993) Acta Chimica Sinica 51:265

    CAS  Google Scholar 

  9. Polynova TN, Smolyar BB, Filippova TF, Porai-Koshits MA, Pirkes SB (1987) Koord Khim 13:130

    CAS  Google Scholar 

  10. Ma JF, Jin ZS, Ni JZ (1993) Acta Chimica Sinica 51:784

    CAS  Google Scholar 

  11. Li X, Zou YQ, Zheng B Hu HM (2004) Acta Cryst C60:m197

    CAS  Google Scholar 

  12. Lam AWH, Wong WT, Gao S, Wen G, Zhang XX (2003) Eur J Inorg Chem 1:149

    Google Scholar 

  13. Li X, Zhang ZY, Wang DY, Zou YQZ (2005) Kristallogr NCS 220:36

    CAS  Google Scholar 

  14. Li X, Zou YQZ (2004) Kristallogr NCS 219:419

    CAS  Google Scholar 

  15. Li X, Zou YQ, Song HB (2004) Acta Cryst C60:m110

    CAS  Google Scholar 

  16. Sheldrick GM (1990) Acta Cryst A46:467

    CAS  Google Scholar 

  17. Sheldrick GM (1997) SHELXL97, Program for X-ray crystal structure solution. University of Göttingen, Germany

    Google Scholar 

Download references

Acknowledgements

We are grateful to the Natural Science Foundation of Beijing (No.2073022).

Author information

Authors and Affiliations

  1. Department of Chemistry, Capital Normal University, Beijing, 100037, China

    Xia Li

  2. Department of Chemistry, Beijing Normal University, Beijing, 100875, China

    Ying-Quan Zou

  3. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China

    Hai-Bin Song

Authors
  1. Xia Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ying-Quan Zou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hai-Bin Song
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xia Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, X., Zou, YQ. & Song, HB. Synthesis and Crystal Structure of Complex [Nd(2-FC6H4COO)3·(2-FC6H4COOH)·H2O]2 . J Chem Crystallogr 37, 555–559 (2007). https://doi.org/10.1007/s10870-007-9210-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-007-9210-0

Keywords

Search

Navigation