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Synthesis, Crystal Structure and Spectral Properties of [Fe3(2,2′-bipy)6(ox)3]·12.25H2O Complex

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Abstract

A novel iron (II) complex of formula [Fe3(2,2′-bipy)6(ox)3]·12.25H2O (2,2′-bipy = 2,2′-bipyridine, ox = oxalate) has been prepared and structurally characterized by X-ray crystallography. In the complex, the metal atoms are six-coordinated in distorted octahedral environment. In the complex [Fe(ox)3]4− anions and water molecules are linked together into 1D chain structure by hydrogen interaction. The red crystal of the complex is monoclinic, space group P21/c, with a = 22.932(6) Å, b = 13.715(4) Å, c = 22.493(6) Å, β = 93.177(5)°, and V = 7063(3) Å3 with Z = 4.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos.20471031, 20471032).

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China

    Xuda Wang, Yunhe Xu, Xueyan Song, Licun Li, Daizheng Liao, Zonghui Jiang & Shiping Yan

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China

    Licun Li

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  1. Xuda Wang
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  2. Yunhe Xu
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  3. Xueyan Song
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Correspondence to Yunhe Xu.

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Wang, X., Xu, Y., Song, X. et al. Synthesis, Crystal Structure and Spectral Properties of [Fe3(2,2′-bipy)6(ox)3]·12.25H2O Complex. J Chem Crystallogr 37, 651–654 (2007). https://doi.org/10.1007/s10870-007-9209-6

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  • DOI: https://doi.org/10.1007/s10870-007-9209-6

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