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A Novel Three Dimensional Organic–Inorganic Hybrid Based Porous Phase: Synthesis and Characterization of Reduced Oxovanadium pyromellitate, [VIV 2O2(H2O)2(C6H2(COO)4)]

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Abstract

The hydrothermal reaction of a mixture of VOSO4 · xH2O, 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid) and 0.1 M H2SO4 for 72 h at 160 °C gives blue needle like crystals of [VIV 2O2(H2O)2(C6H2(COO)4)] in 30% yield. The compound has a porous 3-D extended network structure having a rigid architecture which is held together by the multidentate functionalities of 1,2,4,5-benzenetetracarboxylate ligand. Crystal data for the compound: monoclinic space group C 2/c (No:15), a = 11.756(5) Å, b = 9.645(3) Å, c = 11.822(7) Å, β = 107.10(4)°, Z = 8. The compound constitutes the first example of a fully reduced oxovanadium based solid incorporating the organic ligand. This article consists of synthesis, crystal structure and characterization of [VIV 2O2(H2O)2(C6H2(COO)4)].

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Acknowledgment

This work was partly supported by grants from Afyon Kocatepe University (BAPK-FEF2005-0042) and Turkish State Planning Organization (DPT-2005 K-12060). In addition, the authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayıs University, Turkey, for the use of the Stoe IPDS-2 diffractometer purchased under grant F.279 of the University Research Fund.

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Authors and Affiliations

  1. Department of Chemistry, Science and Literature Faculty, Afyon Kocatepe University, ANS Kampusu, Fen Edebiyat Fakultesi, Kimya Bolumu, Afyonkarahisar, 03200, Turkey

    Sabri Cevik & Mehmet Poyraz

  2. Education Faculty, Department of Physics Education, Gazi University, Besevler-Ankara, 06500, Turkey

    Musa Sarı

  3. Department of Physics, Science and Literature Faculty, Ondokuz Mayıs University, Kurupelit-Samsun, 55139, Turkey

    Orhan Büyükgüngör

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  1. Sabri Cevik
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  2. Mehmet Poyraz
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  4. Orhan Büyükgüngör
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Correspondence to Sabri Cevik.

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Cevik, S., Poyraz, M., Sarı, M. et al. A Novel Three Dimensional Organic–Inorganic Hybrid Based Porous Phase: Synthesis and Characterization of Reduced Oxovanadium pyromellitate, [VIV 2O2(H2O)2(C6H2(COO)4)]. J Chem Crystallogr 37, 497–502 (2007). https://doi.org/10.1007/s10870-007-9203-z

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