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Hydrogen-Bonding Interactions in the Crystal Structure of Bis(N-propyl-N-(2-hydroxyethyl)dithiocarbamato-S,S′)nickel(II): Ni[S2CN(nPr)(CH2CH2OH)]2

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Abstract

Two independent molecules of Ni(S2CN(Pr)CH2CH2OH)2, each located about a center of inversion, comprise the asymmetric unit. The molecules differ from each other in terms of the relative orientation of the terminal hydroxyl groups. A square planar geometry is found for each nickel atom defined by four sulfur atoms derived from two symmetrically chelating dithiocarbamate ligands. The crystal packing is dominated by O–H···O interactions that lead to extensive cross linking in all directions. The compound crystallizes in the triclinic space group P-1 with a = 6.4008(11) Å, b = 11.480(2) Å, c = 12.517(2) Å, α = 88.021(2)°, β = 82.491(2)°, γ = 89.986(2)°, and Z = 2.

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Acknowledgments

We acknowledge Prof. Bill Clegg and the synchrotron component, at Daresbury, of the EPSRC National Crystallography Service, based at the University of Southampton, UK, for data collection.

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Authors and Affiliations

  1. Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, San Antonio, TX, 78249-0698, USA

    Edward R. T. Tiekink & James L. Wardell

  2. Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen, AB24 3UE, Scotland

    James L. Wardell

  3. FioCruz – Fundação Oswaldo Cruz, Instituto de Tecnologia em Fármacos – FarManguinhos, Rua Sizenando Nabuco, 100, Manguinhos, 21041-250, Rio de Janeiro, RJ, Brazil

    Solange M. S. V. Wardell

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  1. Edward R. T. Tiekink
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  3. Solange M. S. V. Wardell
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Correspondence to Edward R. T. Tiekink.

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Tiekink, E.R.T., Wardell, J.L. & Wardell, S.M.S.V. Hydrogen-Bonding Interactions in the Crystal Structure of Bis(N-propyl-N-(2-hydroxyethyl)dithiocarbamato-S,S′)nickel(II): Ni[S2CN(nPr)(CH2CH2OH)]2 . J Chem Crystallogr 37, 439–443 (2007). https://doi.org/10.1007/s10870-007-9189-6

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