The crystal structure of trans-[((bis)triethylphosphine)(bis(phenylselenato))platinum (II)] has been determined by single crystal X-ray diffraction. Crystallization occurs in the triclinic space group P-1 (No. 2) with a = 8.9964(2) Å, b = 11.5103(2) Å, c = 14.9335(3) Å; α = 85.8750(10)°, β = 72.5350(10)°, γ = 68.4450(10)°. Details of the structure and spectroscopic results are presented and discussed and comparisons are made with related square planar platinum (II) structures.
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MDR would like to thank the University of Wisconsin Fox Valley’s Professional Development Committee for their generous funding of this research and to Marquette University for the use of their X-ray diffraction facilities.
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Crystallographic data for the structural analysis of compound 1 has been deposited at the Cambridge Crystallographic Data Center (CCDC number 602972). Copies of the information may be obtained free of charge from The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223-336033; e-mail: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk).
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Rudd, M.D., Lindeman, S.V. Synthesis and characterization of platinum – selenium derivatives: X-ray structure of trans-Pt(PEt3)2(SePh)2 . J Chem Crystallogr 37, 375–379 (2007). https://doi.org/10.1007/s10870-007-9184-y
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DOI: https://doi.org/10.1007/s10870-007-9184-y