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Synthesis and structure of (NH4)4[(DMF)2Mo8O26]· 2CH3CH2OH·2H2O (DMF=N, N-dimethylformamide)

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Abstract

A new organic-inorganic hybrid γ-octamolybdate complex, (NH4)4[(C3H7NO)2Mo8O26]·2CH3CH2OH·2H2O was synthesized from the mixture of ethanol, DMF, 4-aminobenzoic acid, (NH4)6Mo7O24·4H2O, HCl and H2O. The structure was determined by X-ray crystallography. It crystallizes in monoclinic P21/n space group with the crystal cell parameters of a = 8.8825(4), b = 21.1608(10), c = 11.1343(6) Å, β = 104.7720(10)°, V = 2023.64(17) Å3 and Z = 2. The crystal X-ray analysis shows that two DMF molecules are bound to γ-octamolybdate anion. The molecular structure is stabilized by the complex hydrogen bonding.

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References

  1. Müller, A.; Reuter, H.; Dillinger, S. Angew. Chem., Int. Ed. Engl. 1995, 34, 2328.

    Article  Google Scholar 

  2. Pope, M.T.; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34.

    Article  Google Scholar 

  3. Hagrman, D.; Haushalter, R.C.; Zubieta, J. J. Chem. Mater. 1998, 10, 361.

    Article  CAS  Google Scholar 

  4. Yaghi, Q.M. Nature 1999, 402, 276.

    Article  Google Scholar 

  5. Stupp, S.I.; Braun, P.V. Science 1997, 277, 1242.

    Article  CAS  Google Scholar 

  6. Pope, M.T. Heteropoly and Isopoly Oxometalates, Springer, New York, 1983.

    Google Scholar 

  7. Xi, R.; Wang, B.; Isobe, K.; Nishioka, T.; Toriumi, K.; Ozawa, Y. Inorg. Chem. 1994, 33, 833.

    Article  CAS  Google Scholar 

  8. Hagrman, D.; Zubieta, C.; Rose, D.J.; Zubieta, J.; Haushalter, R.C. Angew. Chem. Int. Ed. Engl. 1997, 36, 873.

    Article  CAS  Google Scholar 

  9. Sun, J.Y.; Wang, L.H.; Zhou, Y.M.; Chen, J.X.; Liu, Z.C.; Zhao, D.Y. Angew. Chem. Int. Ed. Engl. 2002, 41, 4471.

    Article  CAS  Google Scholar 

  10. Sheldrick, G.M. SADABS; Siemens Analytical X-ray Instrument Division, Madison, WI, 1995.

  11. Sheldrick, G.M. SHELXL-97: Program for Crystal Structure Refinement. University of Göttingen, Germany, 1997.

    Google Scholar 

  12. Adams, R.D.; Klemperer, W.G.; Liu, R.S. J. Chem. Soc., Chem. Commun. 1979, 256.

  13. Chen, Z.F.; Liu, B.; Liang, H.; Hu, R.X.; Zhou, Z.Y. Chinese J. Struct. Chem. 2004, 23, 19.

    CAS  Google Scholar 

  14. Yamase, T.; Inoue, M.; Naruke, H.; Fukaya, K. Chem. Lett. 1999, 563.

  15. Wang, S.; Lin, X.; Lu, C.Z.; Wu, D.M.; Yang, W.B. Chinese J. Struct. Chem. 2000, 19, 191.

    Google Scholar 

  16. Liu, G.; Zhang, S.W.; Tang, Y.Q. Z. Anorg. Allg. Chem. 2001, 627, 1077.

    Article  CAS  Google Scholar 

  17. Lu, J.; Xu, Y. Chem. Mater. 1998, 10, 4141.

    Article  CAS  Google Scholar 

  18. You, X.; Chen, J.; Xu, Z.; Huang, J. Acta Cryst. 1989, C45, 413.

    CAS  Google Scholar 

  19. Inoue, M.; Yamase, T. Bull. Chem. Soc. Jpn. 1995, 68, 3055.

    Article  CAS  Google Scholar 

  20. Roman, P.; Luque, A.; Aranzabe, A.; Gutierrez-Zorrilia, J.M. Polyhedron 1992, 11, 2027.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the start-up fund of Hefei University (600811) and the fund of Anhui Provincial Education Department (KJ2007A014).

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Authors and Affiliations

  1. Department of Chemistry & Materials Engineering, Hefei University, Hefei, 230022, P. R. China

    Quan-Zheng Zhang, Guo-Quan Shao, Gang Chen, Huan Shen, Guo-Hui Lu, Rang Ping, Peng-Fei Xie, Yang Jiang & Jie Zhang

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China

    Quan-Zheng Zhang

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  1. Quan-Zheng Zhang
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  2. Guo-Quan Shao
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  3. Gang Chen
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  6. Rang Ping
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  7. Peng-Fei Xie
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  8. Yang Jiang
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  9. Jie Zhang
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Correspondence to Quan-Zheng Zhang.

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Supplementary material

Crystallographic data for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC 276440. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk.

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Zhang, QZ., Shao, GQ., Chen, G. et al. Synthesis and structure of (NH4)4[(DMF)2Mo8O26]· 2CH3CH2OH·2H2O (DMF=N, N-dimethylformamide). J Chem Crystallogr 37, 369–373 (2007). https://doi.org/10.1007/s10870-007-9183-z

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  • DOI: https://doi.org/10.1007/s10870-007-9183-z

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