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The crystal structure of a bis(2,6-pyridinedicarboxylato)chromate(III) anion with an elaborate network of hydrogen bonding and π stacking

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The synthesis, X-ray crystallography, spectroscopic, and electrochemical properties of the title compound, [Hdpa][Cr(dipic)2]·3H2O, 1, are reported. Compound 1 crystallized in the triclinic space group P-1 with a = 7.1057(11) Å, b = 12.965(2) Å, c = 14.269(2) Å, α = 80.306(3)°, β = 82.101(2)°, γ = 83.799(2)°, and V = 1278.6(4) Å3 with Z = 2. The distorted octahedral chromium anions are part of an elaborate network of hydrogen bonding formed by the waters of solvation, the anion, and cation as well as π-stacking interactions.

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Acknowledgments

Vince C.R. Payne would like to thank the University of the West Indies, Cave Hill Campus, Barbados for its financial support.

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Authors and Affiliations

  1. Department of Biological and Chemical Sciences, University of the West Indies, Cave Hill Campus, P.O. Box 64, Bridgetown, St. Michael, Barbados

    Vince C. R. Payne, Oliver St. C. Headley & Anthony M. Newton

  2. Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ, 08854, USA

    Robert T. Stibrany

  3. Department of Chemistry, University of the West Indies, Mona Campus, Mona, St. Andrew, Kingston, 7, Jamaica

    Paul T. Maragh & Tara P. Dasgupta

  4. Department of Chemistry and Biochemistry, The University of Southern Mississippi, 118 College Drive, # 5043, Hattiesburg, MS, 39406-0001, USA

    Alvin A. Holder

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  1. Vince C. R. Payne
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Correspondence to Robert T. Stibrany or Alvin A. Holder.

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Payne, V.C.R., Headley, O.S.C., Stibrany, R.T. et al. The crystal structure of a bis(2,6-pyridinedicarboxylato)chromate(III) anion with an elaborate network of hydrogen bonding and π stacking. J Chem Crystallogr 37, 309–314 (2007). https://doi.org/10.1007/s10870-007-9181-1

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  • DOI: https://doi.org/10.1007/s10870-007-9181-1

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