Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne and imidazole with Cu(II) produces crystals containing a discrete complex of [μ-4,4′-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)-N, O, O′-μ-N′, O′′, O′′′]-diaqua-bis(imidazole)-dicopper(II) complex (1), [(C16H4N2O8)(C3H4N2)2(H2O)2Cu2] instead of a linear coordination polymer. The complex crystallizes in the monoclinic space group P21/n with a = 5.3763(8) Å, b = 18.522(3) Å, c = 11.4827(7) Å, β = 93.705(3) ° and Z = 2. The complex sits on a center of symmetry such that the two halves of the molecule are related by inversion symmetry. The molecules pack in layers in which the molecules are joined by intermolecular N–H⋯O hydrogen bonds between imidazole and carboxylate groups and O–H⋯O hydrogen bonds between carboxylate groups and water.
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Acknowledgement is made to the U. S. Army Research Office (grant # W911NF-05-0293) and to the Donors of The Petroleum Research Fund (grant # 34604-B3), administered by the American Chemical Society, for support of this research at Worcester Polytechnic Institute.
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Supplementary Materials CCDC 615638 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via by e-mailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK, Fax: +44(0)1223−336033.
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Wang, Y., Cooper, C.G.F., Luisi, B.S. et al. Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne and imidazole with Cu(II) generates a discrete complex not a coordination polymer: crystal structure of [μ-4,4′-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)-N, O, O′-μ-N′, O′′, O′′′]-diaqua-bis(imidazole)-dicopper(II). J Chem Crystallogr 37, 299–308 (2007). https://doi.org/10.1007/s10870-007-9179-8
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DOI: https://doi.org/10.1007/s10870-007-9179-8